A Lanthanide Luminescent Cation Exchange Material Derived from a Flexible Tricarboxylic Acid 2,6-Bis(1,2,3-triazol-4-yl)pyridine (btp) Tecton

被引:17
作者
McCarney, Eoin P. [1 ,2 ]
Hawes, Chris S. [1 ,2 ]
Kitchen, Jonathan A. [3 ,6 ]
Byrne, Kevin [4 ,5 ]
Schmitt, Wolfgang [4 ,5 ]
Gunnlaugsson, Thorfinnur [1 ,2 ]
机构
[1] Univ Dublin, Trinity Coll Dublin, Sch Chem, Dublin D02 R590 2, Ireland
[2] Univ Dublin, Trinity Coll Dublin, TBSI, Dublin D02 R590 2, Ireland
[3] Univ Southampton, Chem, Southampton SO17 1BJ, Hants, England
[4] Univ Dublin, Trinity Coll Dublin, Sch Chem, Dublin D02 XR15 2, Ireland
[5] Univ Dublin, Trinity Coll Dublin, CRANN, Dublin D02 XR15 2, Ireland
[6] Massey Univ Albany, Inst Nat & Math Sci, Auckland 0745, New Zealand
基金
爱尔兰科学基金会; 欧洲研究理事会;
关键词
METAL-ORGANIC FRAMEWORKS; SELF-ASSEMBLY FORMATION; TO-CHELATE APPROACH; CLICK CHEMISTRY; COORDINATION POLYMERS; LINKER SUBSTITUTION; SUPRAMOLECULAR GELS; CRYSTAL-STRUCTURES; RU(II) COMPLEXES; BUILDING-BLOCKS;
D O I
10.1021/acs.inorgchem.8b00080
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
The synthesis of the three-dimensional metal-organic framework material, [Zn7L6]center dot(H2NMe2)(4)center dot(H2O)(45) (1), derived from a flexible tricarboxylic acid 2,6-bis(1,2,3-triazol-4-yl)pyridine (btp) ligand, is presented. The btp ligand, H3L, adopts a three-dimensional hydrogen bonding network in the crystalline state through a combination of carboxylic acid dimer and syn-anti-btp/carboxylic acid hydrogen bonding synthons. The Zn(II) species 1 exhibits a three-dimensional framework structure with the rare crs topology and contains linear and undulated solvent channels extending in three dimensions. The guest exchange and gas adsorption properties of 1 were investigated; herein we demonstrate the exchange of dimethylammonium cations from the as-synthesized material with cationic guest molecules in the form of dyes and luminescent Ln(III) ions. Sensitization of Eu(III) and Tb(III) inside the porous network of 1 was achieved upon cation exchange, with a view toward developing functional luminescent materials.
引用
收藏
页码:3920 / 3930
页数:11
相关论文
共 101 条
  • [61] Synthesis and structural studies of 1,4-di(2-pyridyl)-1,2,3-triazole dpt and its transition metal complexes; a versatile and subtly unsymmetric ligand
    McCarney, Eoin P.
    Hawes, Chris S.
    Blasco, Salvador
    Gunnlaugsson, Thorfinnur
    [J]. DALTON TRANSACTIONS, 2016, 45 (25) : 10209 - 10221
  • [62] Self-assembly formation of a healable lanthanide luminescent supramolecular metallogel from 2,6-bis(1,2,3-triazol-4-yl)pyridine (btp) ligands
    McCarney, Eoin P.
    Byrne, Joseph P.
    Twamley, Brendan
    Martinez-Calvo, Miguel
    Ryan, Gavin
    Moebius, Matthias E.
    Gunnlaugsson, Thorfinnur
    [J]. CHEMICAL COMMUNICATIONS, 2015, 51 (74) : 14123 - 14126
  • [63] Ag(I)-based tectons for the construction of helical and meso-helical hydrogen-bonded coordination networks
    McMorran, David A.
    [J]. INORGANIC CHEMISTRY, 2008, 47 (02) : 592 - 601
  • [64] Helicity inversion in responsive foldamers induced by achiral halide ion guests
    Meudtner, Robert M.
    Hecht, Stefan
    [J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2008, 47 (26) : 4926 - 4930
  • [65] Responsive backbones based on alternating triazole-pyridine/benzene copolymers: From helically folding polymers to metallosupramolecularly crosslinked gels
    Meudtner, Robert M.
    Hecht, Stefan
    [J]. MACROMOLECULAR RAPID COMMUNICATIONS, 2008, 29 (04) : 347 - 351
  • [66] Multifunctional "Clickates" as versatile extended heteroaromatic building blocks: Efficient synthesis via click chemistry, conformational preferences, and metal coordination
    Meudtner, Robert M.
    Ostermeier, Mare
    Goddard, Richard
    Limberg, Christian
    Hecht, Stefan
    [J]. CHEMISTRY-A EUROPEAN JOURNAL, 2007, 13 (35) : 9834 - 9840
  • [67] Design and synthesis of an on-off "click" fluorophore that executes a logic operation and detects heavy and transition metal ions in water and living cells
    Midya, Ganesh Chandra
    Paladhi, Sushovan
    Bhowmik, Sudipta
    Saha, Subhadeep
    Dash, Jyotirmayee
    [J]. ORGANIC & BIOMOLECULAR CHEMISTRY, 2013, 11 (18) : 3057 - 3063
  • [68] Pure and mixed gas adsorption of CH4 and N2 on the metal-organic framework Basolite® A100 and a novel copper-based 1,2,4-triazolyl isophthalate MOF
    Moellmer, Jens
    Lange, Marcus
    Moeller, Andreas
    Patzschke, Christin
    Stein, Karolin
    Laessig, Daniel
    Lincke, Joerg
    Glaeser, Roger
    Krautscheid, Harald
    Staudt, Reiner
    [J]. JOURNAL OF MATERIALS CHEMISTRY, 2012, 22 (20) : 10274 - 10286
  • [69] Fabrication of metal nanoparticles in metal-organic frameworks
    Moon, Hoi Ri
    Lim, Dae-Woon
    Suh, Myunghyun Paik
    [J]. CHEMICAL SOCIETY REVIEWS, 2013, 42 (04) : 1807 - 1824
  • [70] Using metal-ligand interactions for the synthesis of metallostar polymers
    Munuera, Luis
    O'Reilly, Rachel K.
    [J]. DALTON TRANSACTIONS, 2010, 39 (02) : 388 - 391