Comment on "Synthesis, Characterization, and Structures of Persistent Aniline Radical Cation": It Is a Protonated Aniline and Not an Aniline Radical Cation

被引：7
|
作者：
Talipov, Marat R. [1 ]
Hewage, Jeewantha S. [1 ]
Lindeman, Sergey V. [1 ]
Gardinier, James R. [1 ]
Rathore, Rajendra [1 ]
机构：
[1] Marquette Univ, Dept Chem, Milwaukee, WI 53201 USA
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2014年 / 53卷 / 04期
基金：
美国国家科学基金会;
关键词：
anilines; Jahn-Teller effect; radical cations; spin contamination; RAY CRYSTALLOGRAPHIC EVIDENCE; CHARGE DELOCALIZATION; MOLECULES;
D O I：
10.1002/anie.201305293
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The same, but different: The reaction of tri-tert-butylaniline (TBA) with AgSbF6 in CH2Cl2 produces a green-colored intermediate which undergoes decomposition to form a protonated aniline (TBAH+SbF6-). Crystals of the protonated aniline salt (see picture) were analyzed by X-ray diffraction and found to have the same crystal characteristics as the crystals of the supposed cation radical first identified in 2012. Copyright © 2014 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
引用
收藏
页码：938 / 942
页数：5
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