Single-crystal CeCl3(CH3OH)4: A new metal-organic cerium chloride methanol adduct for scintillator applications

被引：10

作者：

Boatner, L. A. ^{[1
]}

Wisniewski, D. ^{[1
]}

Neal, J. S. ^{[1
]}

Ramey, J. O. ^{[1
]}

Kolopus, J. A. ^{[1
]}

Chakoumakos, B. C. ^{[2
]}

Wisniewska, M. ^{[1
]}

Custelcean, R. ^{[3
]}

机构：

[1] Oak Ridge Natl Lab, ORNL Ctr Radiat Detect Mat & Syst, Oak Ridge, TN 37831 USA

[2] Oak Ridge Natl Lab, Neutron Scattering Sci Div, Oak Ridge, TN 37831 USA

[3] Oak Ridge Natl Lab, Div Chem Sci, Oak Ridge, TN 37831 USA

来源：

APPLIED PHYSICS LETTERS | 2008年 / 93卷 / 24期

关键词：

crystal growth from solution; gamma-ray detection; luminescence; neutron detection; organometallic compounds; photon counting; solid scintillation detectors; X-ray detection;

D O I：

10.1063/1.3049137

中图分类号：

O59 [应用物理学];

学科分类号：

摘要：

A new scintillator material consisting of a methanol adduct of cerium trichloride with the composition CeCl3(CH3OH)(4) has been discovered and crystallized in the form of large single crystals by solution growth in methanol. The peak emission of the x-ray-excited luminescence spectrum occurs at similar to 364 nm. A light yield of up to similar to 16 600 photons/MeV and an energy resolution of 11.4% were obtained using 662 keV gamma-ray photons. The scintillator decay time for 662 keV gamma-ray excitation was measured using the time-correlated, single-photon-counting method, and a nominal value of 64.4 ns was obtained. The molecular adduct CeCl3(CH3OH)(4) represents the first example of a rare-earth, metal-organic scintillator that is applicable to gamma ray, x ray, and neutron detection.

引用

页数：3

共 9 条

[1] YALO3 - CE-FAST-ACTING SCINTILLATORS FOR DETECTION OF IONIZING-RADIATION [J].

BARYSHEVSKY, VG ;

KORZHIK, MV ;

MOROZ, VI ;

PAVLENKO, VB ;

FYODOROV, AA ;

SMIRNOVA, SA ;

EGORYCHEVA, OA ;

KACHANOV, VA .

NUCLEAR INSTRUMENTS & METHODS IN PHYSICS RESEARCH SECTION B-BEAM INTERACTIONS WITH MATERIALS AND ATOMS, 1991, 58 (02) :291-293

[2] MEASUREMENT OF TIME DEPENDENCE OF SCINTILLATION INTENSITY BY A DELAYED-COINCIDENCE METHOD [J].

BOLLINGER, L ;

THOMAS, GE .

REVIEW OF SCIENTIFIC INSTRUMENTS, 1961, 32 (09) :1044-+

[3] Cerium chloride-methanol adduct crystals, CeCl3(CH3OH)4:: Preparation, crystallography, and scintillation properties [J].

Chakoumakos, B. C. ;

Custelcean, R. ;

Ramey, J. O. ;

Kolopus, J. A. ;

Jin, Rongying ;

Neal, J. S. ;

Wisniewski, D. J. ;

Boatner, L. A. .

CRYSTAL GROWTH & DESIGN, 2008, 8 (07) :2070-2072

[4] Strontium and barium iodide high light yield scintillators [J].

Cherepy, Nerine J. ;

Hull, Giulia ;

Drobshoff, Alexander D. ;

Payne, Stephen A. ;

Van Loef, Edgar ;

Wilson, Cody M. ;

Shah, Kanai S. ;

Roy, Utpal N. ;

Burger, Arnold ;

Boatner, Lynn A. ;

Choong, Woon-Seng ;

Moses, William W. .

APPLIED PHYSICS LETTERS, 2008, 92 (08)

[5] Developing KH2PO4 and KD2 PO4 crystals for the world's most powerful laser [J].

De Yoreo, JJ ;

Burnham, AK ;

Whitman, PK .

INTERNATIONAL MATERIALS REVIEWS, 2002, 47 (03) :113-152

[6]

FINDLEY KO, 2007, P SPIE, V6707

[7] Scintillation properties of LaCl3:Ce3+ crystals:: Fast, efficient, and high-energy resolution scintillators [J].

van Loef, EVD ;

Dorenbos, P ;

Krämer, K ;

Güdel, HU .

IEEE TRANSACTIONS ON NUCLEAR SCIENCE, 2001, 48 (03) :341-345

[8] High-energy-resolution scintillator:: Ce3+ activated LaBr3 [J].

van Loef, EVD ;

Dorenbos, P ;

van Eijk, CWE ;

Krämer, K ;

Güdel, HU .

APPLIED PHYSICS LETTERS, 2001, 79 (10) :1573-1575

[9] Rapid growth of large-scale (40-55 cm) KH2PO4 crystals [J].

Zaitseva, NP ;

DeYoreo, JJ ;

Dehaven, MR ;

Vital, RL ;

Montgomery, KE ;

Richardson, M ;

Atherton, LJ .

JOURNAL OF CRYSTAL GROWTH, 1997, 180 (02) :255-262

← 1 →