Electrochemical and chemical syntheses, structures, and optical properties of the zinc and cadmium complexes in the N,N,O,S-ligand environment

被引：5

作者：

Garnovskii, D. A. ^{[1
]}

Levchenkov, S. I. ^{[1
]}

Aleksandrov, G. G. ^{[2
]}

Makarova, N. I. ^{[3
]}

Vlasenko, V. G. ^{[4
]}

Zubavichus, Ya. V. ^{[5
]}

Uraev, A. I. ^{[3
]}

Burlov, A. A. ^{[3
]}

机构：

[1] Russian Acad Sci, Southern Sci Ctr, Rostov Na Donu, Russia

[2] Russian Acad Sci, Kurnakov Inst Gen & Inorgan Chem, Moscow 119991, Russia

[3] Southern Fed Univ, Phys & Organ Chem Res Inst, Rostov Na Donu, Russia

[4] Southern Fed Univ, Phys Res Inst, Rostov Na Donu, Russia

[5] Russian Res Ctr, Kurchatov Inst, Moscow 123182, Russia

来源：

RUSSIAN JOURNAL OF COORDINATION CHEMISTRY | 2016年 / 42卷 / 12期

关键词：

electrosynthesis; N; S-tridentate Schiff base; metallochelates; binuclear complex; optical properties; X-RAY; NICKEL(II) COMPLEXES; ACTIVE-CENTERS; SCHIFF-BASE; COPPER(II); PROTEINS; LIGANDS;

D O I：

10.1134/S1070328416120010

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The chemical and electrochemical syntheses of the zinc (I) and cadmium (II) complexes are carried out on the basis of the tridentate Schiff base (H2L), the condensation product of (2-tosylaminoaniline) N-(2-aminophenyl)-4-methylbenzenesulfunamide with 1-phenyl-3-methyl-4-formylpyrazole-5-thiol. The structures and compositions of the synthesized metallochelates are proved by the data of C, H, and N elemental analyses, IR spectroscopy, and H-1 NMR spectroscopy. X-ray absorption spectroscopy is used to determine the structure of the zinc complex. The binuclear structure of the cadmium complex is confirmed by the X-ray diffraction data (CIF file CCDC no. 1471159). The optical properties of H2L and the zinc and cadmium complexes in dimethyl sulfoxide (DMSO) solutions are studied.

引用

页码：755 / 762

页数：8

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