Bis{1-[(E)-2-pyridinylmethylidene]semi-carbazide}cobalt(II) diperchlorate monohydrate

被引：20
|
作者：
Zhou, J [1 ]
Chen, ZF [1 ]
Tan, YS [1 ]
Wang, XW [1 ]
Tan, YH [1 ]
Liang, H [1 ]
Zhang, Y [1 ]
机构：
[1] Guangxi Normal Univ, Coll Chem & Chem Engn, Guilin 541004, Peoples R China
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2004年 / 60卷
关键词：
D O I：
10.1107/S1600536804007494
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
The Co atom in the title complex, [Co(C7H8N4O)(2)]-(ClO4)(2).H2O, is octahedrally coordinated by two molecules of the neutral Schiff bases derived from the condensation of pyridine-2-carbaldehyde and semicarbazone; the Schiff base molecules act as meridional tridentate ligands, coordinating the metal through the amido O atom, imine N and pyridyl N atoms. The ligands are perpendicular to each other [ dihedral angle = 87.27 (5)degrees]. The crystal packing is stabilized by intermolecular hydrogen bonds involving the cations, perchlorate counter-ions and water molecules.
引用
收藏
页码：M519 / M521
页数：3
相关论文
共 50 条
  • [1] Synthesis and crystal structures of bis(1-{(E)-2-pyridinylmethylidene}-semicarbazone)iron(II) and copper(II) diperchlorate monohydrates
    Garbelini, Ellery R.
    Horner, Manfredo
    Behm, Mariana Boneberger
    Evans, David J.
    Nunes, Fabio S.
    ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 2008, 634 (10): : 1801 - 1806
  • [2] Synthesis, characterization and chemical properties of 1-((E)-2-pyridinylmethylidene)semicarbazone manganese(II) and iron(II) complexes
    Garbelini, Ellery Regina
    Martin, Maria da Graca M. B.
    Back, Davi Fernando
    Evans, David John
    Mueller-Santos, Marcelo
    Ribeiro, Ronny Rocha
    Lang, Ernesto Schulz
    Nunes, Fabio Souza
    JOURNAL OF MOLECULAR STRUCTURE, 2012, 1008 : 35 - 41
  • [3] Structural, Magnetic, Spectroscopic and Density Functional Theory (DFT) Analysis of Bis ((1-((E)-2-pyridinylmethylidene) semicarbazone) copper(II) sulfate) Dihydrate Complex
    Soek, Rafael N.
    Gouveia, Tiago L. da C.
    Garbelini, Ellery R.
    Crespan, Estela dos R.
    Pineider, Francesco
    Poneti, Giordano
    Machado, Guilherme S.
    Ribeiro, Ronny R.
    Horner, Manfredo
    Nunes, Fabio S.
    CHEMISTRYSELECT, 2017, 2 (27): : 8451 - 8458
  • [4] Structure and magnetic properties of two new lanthanide complexes with the 1-((E)-2-pyridinylmethylidene) semicarbazone ligand
    Soek, Rafael Natan
    Ferreira, Caroline Mariano
    Santana, Francielli Sousa
    Hughes, David L.
    Poneti, Giordano
    Ribeiro, Ronny Rocha
    Nunes, Fabio Souza
    JOURNAL OF MOLECULAR STRUCTURE, 2019, 1184 : 254 - 261
  • [5] Synthesis, Crystal Structure and Spectroscopic Properties of Bis(1-(E)-2-formylpyridine semicarbazone)nickel(II) Diperchlorate Monohydrate
    Garbelini, Ellery R.
    Hoerner, Manfredo
    Giglio, Vinicius F.
    da Silva, Aline H.
    Barison, Andersson
    Nunes, Fabio S.
    ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 2009, 635 (08): : 1236 - 1241
  • [6] STRUCTURE OF CIS-DIAQUA-BIS(2,2′-BIPYRIMIDINE) COBALT(II) DIPERCHLORATE MONOHYDRATE.
    Brunzelle, J. S.
    Wang, Y.
    Fitch, A.
    Pavkovic, S. F.
    ACTA CRYSTALLOGRAPHICA A-FOUNDATION AND ADVANCES, 1996, 52 : C298 - C298
  • [7] Preparation, crystallography and spectroscopic properties of the polymeric {(1-(E)-2-pyridinylmethylidene)semicarbazone)(aqua)copper(II)} sulphate clihydrate complex: Evidence of dynamic Jahn Teller effect
    Garbelini, Ellery R.
    Ribeiro, Ronny Rocha
    Hoerner, Manfredo
    Locatelli, Aline
    Nunes, Fabio S.
    SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY, 2011, 78 (05) : 1337 - 1341
  • [8] STRUCTURES OF (2-CYANOETHYL)(3-CYANOPYRIDINE)BIS(DIMETHYLGLYOXIMATO(1-)COBALT(III) MONOHYDRATE (I) AND (4-AMINOPYRIDINE)(2-CYANOETHYL)-BIS(DIMETHYLGLYOXIMATO(1-))COBALT(III) (II)
    SEKINE, A
    OHASHI, Y
    HORI, K
    ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1991, 47 : 525 - 528
  • [9] Bis(μ-2-{1-[2-(dimethylamino)ethylimino]ethyl}phenolato)bis[bromidocopper(II)] monohydrate
    Gwaram, Nura Suleiman
    Khaledi, Hamid
    Ali, Hapipah Mohd
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2011, 67 : M931 - U1039
  • [10] Bis[tris(2-aminoethyl)amine]cobalt(II) Bis[tetracarbonylcobaltate(1-)]
    Acta Crystallogr Sect C Cryst Struct Commun, pt 6 (757-760):
12345