Quantum effects in the capture of charged particles by dipolar polarizable symmetric top molecules. II. Interplay between electrostatic and gyroscopic interactions

被引：10

作者：

Auzinsh, M. ^{[1
]}

Dashevskaya, E. I. ^{[2
,3
]}

Litvin, I. ^{[3
]}

Nikitin, E. E. ^{[2
,3
]}

Troe, J. ^{[3
,4
]}

机构：

[1] Univ Latvia, Dept Phys, LV-1586 Riga, Latvia

[2] Technion Israel Inst Technol, Schulich Fac Chem, IL-32000 Haifa, Israel

[3] Max Planck Inst Biophys Chem, D-37077 Gottingen, Germany

[4] Univ Gottingen, Inst Phys Chem, D-37077 Gottingen, Germany

来源：

JOURNAL OF CHEMICAL PHYSICS | 2013年 / 139卷 / 14期

关键词：

ADIABATIC CHANNEL MODEL; MUTUAL CAPTURE; METHANE; MOMENT;

D O I：

10.1063/1.4821589

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Within the general axially nonadiabatic channel approach described in Paper I of this series [M. Auzinsh, E. I. Dashevskaya, I. Litvin, E. E. Nikitin, and J. Troe, J. Chem. Phys. 139, 084311 (2013)], the present article analyzes the simultaneous manifestation of electrostatic and gyroscopic interactions in the quantum capture of dipolar polarizable symmetric top molecules by ions. As a demonstration, the rate coefficients for capture of CH3D and CD3H by H+, D+, and H-3(+) are calculated. (C) 2013 AIP Publishing LLC.

引用

页数：10

共 2 条

[1] Quantum effects in the capture of charged particles by dipolar polarizable symmetric top molecules. I. General axially nonadiabatic channel treatment
Auzinsh, M.
Dashevskaya, E. I.
Litvin, I.
Nikitin, E. E.
Troe, J.
JOURNAL OF CHEMICAL PHYSICS, 2013, 139 (08):
[2] Quantum capture of charged particles by rapidly rotating symmetric top molecules with small dipole moments: analytical comparison of the fly-wheel and adiabatic channel limits
Auzinsh, M.
Dashevskaya, E. I.
Nikitin, E. E.
Troe, J.
MOLECULAR PHYSICS, 2013, 111 (14-15) : 2003 - 2011

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