UV-cured transparent magnetic polymer nanocomposites

被引：31

作者：

Nardi, Tommaso ^{[1
]}

Sangermano, Marco ^{[2
]}

Leterrier, Yves ^{[1
]}

Allia, Paolo ^{[2
]}

Tiberto, Paola ^{[3
]}

Manson, Jan-Anders E. ^{[1
]}

机构：

[1] Ecole Polytech Fed Lausanne, Lab Technol Composites & Polymeres LTC, CH-1015 Lausanne, Switzerland

[2] Politecn Torino, DISAT, I-10129 Turin, Italy

[3] INRIM, Electromagnetism Div, I-10135 Turin, Italy

来源：

POLYMER | 2013年 / 54卷 / 17期

基金：

瑞士国家科学基金会;

关键词：

Core/shell nanoparticles; Magnetic materials; Photopolymerization; HAMAKER CONSTANTS; FACILE SYNTHESIS; NANOPARTICLES; COATINGS;

D O I：

10.1016/j.polymer.2013.06.052

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Magnetite nanoparticles are synthesized by thermal decomposition of Fe(acac)(3) and subsequently coated with a silica shell exploiting a water-in-oil synthetic procedure. The as-produced nanopowder is mixed with a photocurable hyperbranched resin and the polymerization process is studied by means of real-time FTIR (RT-FTIR). Owing to the presence of the silica shell, the photocuring ability of the systems containing core-shell structures is highly improved compared with that of the formulations filled with bare magnetite nanoparticles, allowing the efficient polymerization of a 100 mu m-thick film loaded with an unprecedented 8 vol% of magnetic filler. (c) 2013 Elsevier Ltd. All rights reserved.

引用

页码：4472 / 4479

页数：8

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