Towards solvent-controlled reactivity in ionic liquids

被引：40

作者：

Yau, Hon Man ^{[1
]}

Keaveney, Sinead T. ^{[1
]}

Butler, Bradley J. ^{[1
]}

Tanner, Eden E. L. ^{[1
]}

Guerry, Max S. ^{[1
]}

George, Stephen R. D. ^{[1
]}

Dunn, Michelle H. ^{[1
]}

Croft, Anna K. ^{[2
]}

Harper, Jason B. ^{[1
]}

机构：

[1] Univ New S Wales, Sch Chem, Unsw Sydney 2052, Australia

[2] Univ Nottingham, Process & Environm Res Div, Dept Chem & Environm Engn, Nottingham NG7 2RD, England

来源：

PURE AND APPLIED CHEMISTRY | 2013年 / 85卷 / 10期

关键词：

ionic liquids; reaction control; reaction mechanisms; solvation; solvent effects; TEMPERATURE MOLTEN-SALTS; AROMATIC-COMPOUNDS; DYNAMICS; CATALYST; WATER;

D O I：

10.1351/PAC-CON-12-10-22

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Ionic liquids are frequently touted as alternatives to traditional molecular solvents but are limited in their applicability as the outcome of reactions may be altered on moving from a molecular to an ionic solvent. This manuscript summarizes our progress towards a predictive framework through understanding how ionic solvents affect organic processes, with an emphasis on how these findings might be applied. Particularly, we will consider the importance of the mole fraction of the ionic liquid used, including some hitherto undisclosed results, as well as the importance of understanding the key interactions of the solvent with the components along the reaction coordinate.

引用

页码：1979 / 1990

页数：12

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