A Dodecanuclear Dysprosium Wheel Assembled by Six Vertex-Sharing Dy3 Triangles Exhibiting Slow Magnetic Relaxation

被引：94
作者：
Zhao, Lang [1 ]
Xue, Shufang [1 ]
Tang, Jinkui [1 ]
机构：
[1] Chinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Rare Earth Resource Utilizat, Changchun 130022, Peoples R China
来源：
INORGANIC CHEMISTRY | 2012年 / 51卷 / 11期
基金：
中国国家自然科学基金;
关键词：
SINGLE-MOLECULE MAGNET; GROUND-STATE; CLUSTERS; SYMMETRY; COMPLEX;
D O I：
10.1021/ic3005807
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Reactions of lanthanide(III) (Ln(III)) perchlorate (Ln = Dy and Ho) and a polydentate Schiff base resulted in the unprecedented assembly of novel Ln(12) wheels containing six vertex-sharing Ln(3) triangles. The Dy-12 derivative represents the largest lanthanide wheel based on the peculiar Dy-3 triangles showing slow magnetic relaxation.
引用
收藏
页码：5994 / 5996
页数：3
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