Electrical double layer at zirconium silicate/electrolyte solution interface

被引：0
作者：
Janusz, W [1 ]
Skwarek, E [1 ]
Galgan, A [1 ]
机构：
[1] Marie Curie Sklodowska Univ, Dept Radiochem & Colloid Chem, PL-20031 Lublin, Poland
来源：
POLISH JOURNAL OF CHEMISTRY | 2002年 / 76卷 / 05期
关键词：
zirconium silicate; electrical double layer; pzc; iep;
D O I：
暂无
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Parameters of the electrical double layer at zirconium silicate/aqueous sodium chloride interface were estimated from potentiometric titrations, background electrolyte ions adsorption and electrophoretic measurements data. Using numerical optimization the ionization and complexation constants of surface hydroxyl groups were determined. The best fit of calculations to the experimental data was achieved by assuming two kinds of surface hydroxyl groups that differ in acid-base properties.
引用
收藏
页码：745 / 754
页数：10
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