SYNTHESIS, GROWTH AND CHARACTERIZATION OF L-VALINE ZINC HYDROCHLORIDE - A NOVEL SEMI-ORGANIC NONLINEAR OPTICAL SINGLE CRYSTAL

被引:16
作者
Jananakumar, Deepa [1 ]
Mani, P. [2 ]
机构
[1] Velalar Coll Engn & Technol, Dept Phys, Erode 638012, India
[2] Hindustan Univ, Dept Phys, Madras 603103, Tamil Nadu, India
关键词
Slow evaporation technique; X-ray diffraction; Vickers microhardness; laser damage threshold; second harmonic generation; L-ARGININE PHOSPHATE; L-ALANINE; 2ND-HARMONIC GENERATION; CADMIUM CHLORIDE; AMINO-ACIDS; TETRAFLUOROBORATE; HYDROBROMIDE;
D O I
10.1142/S0218863513500161
中图分类号
O43 [光学];
学科分类号
070207 ; 0803 ;
摘要
Single crystals of L-valine zinc hydrochloride (LVZHCl), a novel semi-organic nonlinear optical material were synthesized and grown from aqueous solution by slow evaporation method at room temperature. The cell parameters of LVZHCl had been determined using single crystal X-ray diffraction technique. The linear and non-linear optical properties of the crystals were studied by Fourier Transform Infrared, Ultraviolet Visible Near infrared, ac impedance, laser damage threshold, and second harmonic generation analysis. The thermal stability of the crystals was assessed by Differential thermal-Thermogravimetric analysis. The crystallinity and mechanical properties of the crystals were studied by Dielectric behavior and Vickers microhardness test.
引用
收藏
页数:17
相关论文
共 45 条
[1]   Bulk single crystal growth and characterization of L-leucine - A nonlinear optical material [J].
Adhikari, Soma ;
Kar, Tanusree .
MATERIALS CHEMISTRY AND PHYSICS, 2012, 133 (2-3) :1055-1059
[2]   Solution growth of a novel nonlinear optical material: L-histidine tetrafluoroborate [J].
Aggarwal, MD ;
Choi, J ;
Wang, WS ;
Bhat, K ;
Lal, RB ;
Shields, AD ;
Penn, BG ;
Frazier, DO .
JOURNAL OF CRYSTAL GROWTH, 1999, 204 (1-2) :179-182
[3]  
Anderson J.C., 1964, DIELECTRICS
[4]  
[Anonymous], 1987, Nonlinear Optical Properties of Organic a. Molecules and Crystals
[5]  
[Anonymous], J MIN MAT CHAR ENG
[6]  
BALAREW C, 1984, J SOLID STATE CHEM, V55, P1, DOI 10.1016/0022-4596(84)90240-8
[7]  
Bellamy J, 1995, INFRARED SPECTRA COM
[8]   Study of laser induced damage threshold and effect of inclusions in some nonlinear crystals [J].
Bhar, GC ;
Chaudhary, AK ;
Kumbhakar, P .
APPLIED SURFACE SCIENCE, 2000, 161 (1-2) :155-162
[9]   Growth, optical, thermal and dielectric studies of an amino acid organic nonlinear optical material: L-Alanine [J].
Caroline, M. Lydia ;
Sankar, R. ;
Indirani, R. M. ;
Vasudevan, S. .
MATERIALS CHEMISTRY AND PHYSICS, 2009, 114 (01) :490-494
[10]  
Chandrasekaran J., 2011, RASAYAN J CHEM, V4, P320