Preparation, characterization, and thermal properties of the microencapsulation of a hydrated salt as phase change energy storage materials

被引:117
作者
Huang, Jin [1 ]
Wang, Tingyu [1 ]
Zhu, Panpan [1 ]
Xiao, Junbin [1 ]
机构
[1] Guangdong Univ Technol, Sch Mat & Energy, Guangzhou 510006, Guangdong, Peoples R China
基金
中国国家自然科学基金;
关键词
Microencapsulated phase change materials; Hydrated salt; Thermal properties; Thermal energy storage; FABRICATION; NA2HPO4-CENTER-DOT-12H(2)O; SOLVENT;
D O I
10.1016/j.tca.2013.01.019
中图分类号
O414.1 [热力学];
学科分类号
摘要
Microcapsules loaded by disodium hydrogen phosphate heptahydrate (Na2HPO4.7H(2)O) were prepared by means of the suspension copolymerization-solvent volatile method, with modified polymethylmethacrylate (PMMA) as coating polymer under the conditions of various organic solvents. The formation of the microencapsulated phase change materials (MEPCMs)-PMMA/Na2HPO4-7H(2)O was investigated and analyzed. The morphology of the resultant materials was characterized by using scanning electron microscope (SEM) and phase contrast microscope. Its final composition was confirmed by the Fourier transformation infrared (FT-IR). Thermo gravimetric analyzer (TGA) and differential scanning calorimetry (DSC) were adopted to reveal its thermal stability and thermal properties. Results indicated that the materials owned improved subcooling degree and good thermal properties, enabling the materials to be one promising phase change materials for thermal energy storage. (C) 2013 Elsevier B.V. All rights reserved.
引用
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页码:1 / 6
页数:6
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