Zn complex with N-(4′-benzo-15-crown-5)-2(amino-N-tosyl)-phenylaidimine:: Synthesis, crystal structure, and vibration spectrum

被引：7

作者：

Minacheva, LK

Ivanova, IS

Dorokhov, AV

Burlov, AS

Garnovskii, AD

Segienko, VS

Tsivadze, AY

机构：

[1] Russian Acad Sci, NS Kurnakov Gen & Inorgan Chem Inst, Moscow 119991, Russia

[2] Rostov Don State Univ, Inst Phys & Organ Chem, Rostov Na Donu 344104, Russia

[3] Russian Acad Sci, Inst Chem Phys, Moscow 119991, Russia

来源：

RUSSIAN JOURNAL OF COORDINATION CHEMISTRY | 2006年 / 32卷 / 03期

基金：

俄罗斯基础研究基金会;

关键词：

D O I：

10.1134/S107032840603002X

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The ZnL2 complex (I) (HL = N-(4'-benzo-15-crown-5)-2-(amino-N-tosyl)phenylaldimine) is synthesized and studied by IR spectroscopy and X-ray diffraction analysis. The crystals are monoclinic: a = 23.139(2) angstrom. b = 19.931(2) angstrom, c = 14.604(2) angstrom. beta = 121.20(1)degrees. Z = 4. space group C2/c. R = 0.751 tor 766 reflections with l > 2 sigma(l). The Zn atom in a molecule of the complex lies on a twofold axis and is coordinated at the vertices of a distorted tetrahedron by four N atoms of two HL ligands (average Zn-N distance 2.024 angstrom).

引用

页码：166 / 172

页数：7

共 10 条

[1] STRUCTURE OF BENZO-15-CROWN-5 (6,7,9,10,12,13,15,16-OCTAHYDROBENZO[1,4,7,10,13]PENTAOXACYCLOPENTADECIN) AT-150-DEGREES-C [J].