Vibration and two-photon absorption

被引：77
作者：
Bishop, DM [1 ]
Luis, JM
Kirtman, B
机构：
[1] Univ Ottawa, Dept Chem, Ottawa, ON K1N 6N5, Canada
[2] Univ Calif Santa Barbara, Dept Chem & Biochem, Santa Barbara, CA 93106 USA
[3] Univ Girona, Dept Chem, Girona 17071, Catalonia, Spain
[4] Univ Girona, Inst Computat Chem, Girona 17071, Catalonia, Spain
来源：
JOURNAL OF CHEMICAL PHYSICS | 2002年 / 116卷 / 22期
关键词：
D O I：
10.1063/1.1477179
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
A treatment of nuclear vibrational motions in two-photon absorption is laid out in detail. Perturbation theory is used to develop working formulas for diatomic molecules and tested for the X (1)Sigma(+)-A (1)Pi transition of carbon monoxide. The results are compared with the exact numerical values. Certain vibrational contributions, not previously recognized, are found to make an important contribution to the two-photon absorption probability. (C) 2002 American Institute of Physics.
引用
收藏
页码：9729 / 9739
页数：11
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