Si2F6 vibrational spectroscopy revisited

被引:9
作者
Tosa, V [1 ]
Ashimine, K [1 ]
Takeuchi, K [1 ]
机构
[1] RIKEN, INST PHYS & CHEM RES, WAKO, SAITAMA 35101, JAPAN
关键词
hexafluorodisilane; far-infrared spectrum; force field calculations;
D O I
10.1016/S0022-2860(96)09546-4
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The far-infrared spectrum for gaseous Si2F6 has been measured in the spectral range of 10 to 350 cm(-1). The main observed bands have maxima at 38, 104 and 308 cm(-1) and have been assigned to v(4), v(9) and v(8) normal modes, respectively. By using recent spectroscopic values measured by us for the three most abundant isotopomers of Si2F6, we obtained a new set of improved harmonic force field constants for this molecule. (C) 1997 Elsevier Science B.V.
引用
收藏
页码:411 / 414
页数:4
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