High-rate synthesis of Cu-BTC metal-organic frameworks

被引：123
|
作者：
Kim, Ki-Joong [1 ,2 ]
Li, Yong Jun [1 ,2 ]
Kreider, Peter B. [1 ]
Chang, Chih-Hung [1 ,2 ]
Wannenmacher, Nick [1 ]
Thallapally, Praveen K. [3 ]
Ahn, Ho-Geun [4 ]
机构：
[1] Oregon State Univ, Sch Chem Biol & Environm Engn, Corvallis, OR 97331 USA
[2] Oregon Proc Innovat Ctr, Microprod Breakthrough Inst, Corvallis, OR 97330 USA
[3] Pacific NW Natl Lab, Richland, WA 99352 USA
[4] Suncheon Natl Univ, Dept Chem Engn, Sunchon 540742, Jeonnam, South Korea
来源：
CHEMICAL COMMUNICATIONS | 2013年 / 49卷 / 98期
关键词：
MECHANOCHEMICAL SYNTHESIS; CU-3(BTC)(2) HKUST-1; ADSORPTION; POROSITY; SOLIDS; DESIGN; SIZE;
D O I：
10.1039/c3cc46049e
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The reaction conditions for the synthesis of Cu-BTC (BTC = benzene-1,3,5-tricarboxylic acid) were elucidated using a continuous-flow microreactor-assisted solvothermal system to achieve crystal size and phase control. A high-rate synthesis of Cu-BTC metal-organic frameworks with a BET surface area of more than 1600 m(2) g(-1) (Langmuir surface area of more than 2000 m(2) g(-1)) and with a 97% production yield could be achieved with a total reaction time of 5 minutes.
引用
收藏
页码：11518 / 11520
页数：3
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