Biodiesel production from castor oil using heterogeneous Ni doped ZnO nanocatalyst

被引:238
作者
Baskar, G. [1 ]
Selvakumari, I. Aberna Ebenezer [1 ]
Aiswarya, R. [1 ]
机构
[1] St Josephs Coll Engn, Dept Biotechnol, Madras 600119, Tamil Nadu, India
关键词
Biodiesel; Castor oil; Heterogeneous catalysis; Nanocatalyst; Response Surface Methodology; OPTIMIZATION; CATALYSTS; TRANSESTERIFICATION; FEEDSTOCKS; CU;
D O I
10.1016/j.biortech.2017.12.010
中图分类号
S2 [农业工程];
学科分类号
0828 ;
摘要
In the present study, castor oil with high free fatty acid was used for biodiesel production using heterogeneous Ni doped ZnO nanocatalyst. Ni doped ZnO nanocomposite calcinated at 800 degrees C has shown better catalytic activity. Process parameters on heterogeneous catalysis of castor oil into biodiesel were optimized using conventional and Response Surface Methodology (RSM). RSM was found more accurate in estimating the optimum conditions with higher biodiesel yield (95.20%). The optimum conditions for transesterification was found to be oil to methanol molar ratio of 1:8, catalyst loading 11% (w/w), reaction temperature of 55 degrees C for 60 min of reaction time by response surface method. The reusability studies showed that the nanocatalyst can be reused efficiently for 3 cycles.
引用
收藏
页码:793 / 798
页数:6
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