Molecular interaction in a polar-polar system-di-isobutyl ketone (DIBK) and primary aliphatic alcohols - using dielectric measurement

被引：5

作者：

Acharya, S ^{[1
]}

机构：

[1] Ravenshaw Coll, Dept Phys, Cuttack 753003, Orissa, India

来源：

JOURNAL OF MOLECULAR LIQUIDS | 2006年 / 124卷 / 1-3期

关键词：

molecular interaction; DIBK; mutual correlation factor;

D O I：

10.1016/j.molliq.2005.10.002

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Dielectric constant of binary mixtures of di-isobutyl ketone with aliphatic alcohols, namely 1-pentanol, 1-butanol and 1-propanol, is measured at radio frequency 455 kHz and temperature 303.16 K. The data are used to compute mutual correlation factor (g(ab)), excess molar polarization (Delta P) and excess Gibb's free energy (Delta G) in the polar-polar system, with a view to assessing the suitability of alcohol as a modifier. (C) 2005 Elsevier B.V. All rights reserved.

引用

页码：68 / 71

页数：4

共 15 条

[1] Dielectric investigation on a nuclear extractant-acetylacetone (HAA) in nonpolar solvents [J].

Acharya, S ;

Dash, SK ;

Mohanty, JN ;

Swain, BB .

JOURNAL OF MOLECULAR LIQUIDS, 1997, 71 (01) :73-80

[2]

Acharya S., 1998, Indian Journal of Physics, Part B, V72B, P239

[3] Study of molecular interaction in ternary mixture of acetylacetone (HAA) with (benzene plus p-xylene)-linear correlation factor, excess molar polarization and excess Gibb's free energy of mixing [J].

Acharya, S ;

Mishra, S ;

Bhuyan, B ;

Garabadu, K ;

Mohanty, GC .

JOURNAL OF MOLECULAR LIQUIDS, 2004, 109 (01) :33-38

[4] Study of dipolar association in polar-polar system of Di-isobutylketone (DIBK) and carboxylic acids by using dielectric measurement [J].

Acharya, S ;

Mohanty, GC ;

Garabadu, K .

JOURNAL OF THE PHYSICAL SOCIETY OF JAPAN, 2003, 72 (08) :2103-2105

[5] Dipolar interaction in binary polar systems - A dielectric study of acetyl acetone (HAA) and di-iso butyl ketone (DIBK) with some monosubstituted benzenes [J].

Acharya, S ;

Dash, SK ;

Das, JK ;

Swain, BB .

PHYSICS AND CHEMISTRY OF LIQUIDS, 1997, 34 (04) :201-211

[6]

Acharya S, 2003, CHEM PAP, V57, P63

[7] DIELECTRIC POLARIZATION IN MONOHYDRIC ALCOHOLS [J].

BABA, K ;

KAMIYOSHI, KI .

JAPANESE JOURNAL OF APPLIED PHYSICS, 1979, 18 (08) :1639-1640

[8] DIELECTRIC STUDIES ON BINARY-MIXTURES OF TRI-N-BUTYL PHOSPHATE (TBP) AND LONG-CHAIN PRIMARY ALCOHOLS (MODIFIERS) [J].

DASH, SK ;

SWAIN, BB .

JAPANESE JOURNAL OF APPLIED PHYSICS PART 1-REGULAR PAPERS SHORT NOTES & REVIEW PAPERS, 1993, 32 (6A) :2753-2756

[9] PROTACTINIUM .3. SOLVENT EXTRACTION FROM HALIDE SOLUTIONS [J].

GOBLE, AG ;

MADDOCK, AG .

JOURNAL OF INORGANIC & NUCLEAR CHEMISTRY, 1958, 7 (1-2) :94-112

[10]

RAO PRV, 1991, P INT S RAD CHEM RAD

← 1 2 →