Palladium-catalyzed carbonylative cross-coupling reaction of triarylantimony dicarboxylates with arylboronic acids: Synthesis of biaryl ketones

被引：13
|
作者：
Qin, Weiwei [1 ]
Yasuike, Shuji [1 ]
Kakusawa, Naoki [1 ]
Kurita, Jyoji [1 ]
机构：
[1] Hokuriku Univ, Fac Pharmaceut Sci, Org Frontier Res Pharmaceut Sci, Kanazawa, Ishikawa 9201181, Japan
来源：
JOURNAL OF ORGANOMETALLIC CHEMISTRY | 2008年 / 693卷 / 17期
关键词：
triarylantimony diacetate; carbonylative cross-coupling; palladium catalyst; carbon monoxide ( CO); arylboronic acid; biaryl ketone;
D O I：
10.1016/j.jorganchem.2008.05.039
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A novel palladium-catalyzed three- component carbonylative coupling reaction by use of triarylantimony diacetate, arylboronic acid and carbon monoxide ( 1 atm) could be attained under mild reaction conditions without any base as an additive. The reaction can be applied to a wide range of triarylantimony diacetates and boronic acids to afford the corresponding unsymmetrical biaryl ketones in good yields. (c) 2008 Elsevier B. V. All rights reserved.
引用
收藏
页码：2949 / 2953
页数：5
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