Palladium-catalyzed carbonylative cross-coupling reaction of triarylantimony dicarboxylates with arylboronic acids: Synthesis of biaryl ketones

被引：13

作者：

Qin, Weiwei ^{[1
]}

Yasuike, Shuji ^{[1
]}

Kakusawa, Naoki ^{[1
]}

Kurita, Jyoji ^{[1
]}

机构：

[1] Hokuriku Univ, Fac Pharmaceut Sci, Org Frontier Res Pharmaceut Sci, Kanazawa, Ishikawa 9201181, Japan

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 2008年 / 693卷 / 17期

关键词：

triarylantimony diacetate; carbonylative cross-coupling; palladium catalyst; carbon monoxide ( CO); arylboronic acid; biaryl ketone;

D O I：

10.1016/j.jorganchem.2008.05.039

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A novel palladium-catalyzed three- component carbonylative coupling reaction by use of triarylantimony diacetate, arylboronic acid and carbon monoxide ( 1 atm) could be attained under mild reaction conditions without any base as an additive. The reaction can be applied to a wide range of triarylantimony diacetates and boronic acids to afford the corresponding unsymmetrical biaryl ketones in good yields. (c) 2008 Elsevier B. V. All rights reserved.

引用

页码：2949 / 2953

页数：5

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