A Mn(II) coordination framework incorporating the redox-active tris(4-(pyridin-4-yl)phenyl)amine ligand (NPy3): electrochemical and spectral properties

被引：30
|
作者：
Hua, Carol [1 ]
D'Alessandro, Deanna M. [1 ]
机构：
[1] Univ Sydney, Sch Chem, Sydney, NSW 2006, Australia
来源：
CRYSTENGCOMM | 2014年 / 16卷 / 28期
关键词：
METAL-ORGANIC FRAMEWORKS; SINGLE-CRYSTAL; TRI(4-PYRIDYLPHENYL)AMINE LIGAND; CHEMICAL-REDUCTION; TRANSFORMATIONS; TRIARYLAMINES; BINDING;
D O I：
10.1039/c3ce42603c
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A new multifunctional coordination framework, [Mn(NPy3)Cl center dot 3MeOH center dot DMF](n), containing the redox-active tris(4-(pyridine-4-yl)phenyl)amine ligand (NPy3) was synthesised and characterised. The redox properties of the framework were investigated, and the oxidised state of the framework was generated chemically and spectroelectrochemically. This material exhibits multifunctionality by virtue of its ability to switch the fluorescence 'on' and 'off' with the redox state.
引用
收藏
页码：6331 / 6334
页数：4
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