Structural Estimation of Functional Organized Molecular Films by Using Polarized Near-edge X-ray Absorption Fine Structure Spectroscopy

被引:0
作者
Arai, Shuntaro [1 ]
Fujimori, Atsuhiro [1 ]
机构
[1] Saitama Univ, Grad Sch Sci & Engn, Sakura Ku, Saitama 3388570, Japan
关键词
polarized near-edge X-ray absorption fine structure spectroscopy (NEXAFS); organized molecular films; functional copolymers; molecular orientation; intermolecular interaction; FLUORINATED COMB POLYMERS; LANGMUIR-BLODGETT-FILMS; NEXAFS SPECTROSCOPY; SIDE-CHAINS; FLUOROCARBON CHAINS; SINGLE CRYSTALS; CARBAZOLE GROUP; ORIENTATION; MONOLAYER; COPOLYMERS;
D O I
暂无
中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
This paper presents an overview based on the latest topics concerning detailed investigations of the molecular orientation in organized molecular films from the monomolecular layer to the several-layer levels by using polarized near-edge X-ray absorption fine-structure spectroscopy (NEXAFS) while taking advantage of the polarization and absorption of soft X-rays. Especially, while focusing on functional polymers (containing copolymers) having a plurality of functional groups in the molecular structure, an approach for elucidating the ultimate structure formed in sub-nanometer scale spaces is introduced.
引用
收藏
页码:611 / 625
页数:15
相关论文
共 47 条
[1]   RELATIVE REACTIVITIES IN VINYL COPOLYMERIZATION [J].
ALFREY, T ;
PRICE, CC .
JOURNAL OF POLYMER SCIENCE, 1947, 2 (01) :101-106
[2]   STRUCTURAL TRANSITIONS IN A MONOLAYER OF FLUORINATED AMPHIPHILE MOLECULES [J].
BARTON, SW ;
GOUDOT, A ;
BOULOUSSA, O ;
RONDELEZ, F ;
LIN, BH ;
NOVAK, F ;
ACERO, A ;
RICE, SA .
JOURNAL OF CHEMICAL PHYSICS, 1992, 96 (02) :1343-1351
[3]   SELF-ASSEMBLED MONOLAYERS CONTAINING POLYDIACETYLENES [J].
BATCHELDER, DN ;
EVANS, SD ;
FREEMAN, TL ;
HAUSSLING, L ;
RINGSDORF, H ;
WOLF, H .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1994, 116 (03) :1050-1053
[4]   STUFENFORMIGES UND SPIRALFORMIGES KRISTALLWACHSTUM BEI HOCHPOLYMEREN [J].
FISCHER, EW .
ZEITSCHRIFT FUR NATURFORSCHUNG PART A-ASTROPHYSIK PHYSIK UND PHYSIKALISCHE CHEMIE, 1957, 12 (09) :753-754
[5]   Effect of the atoms in outermost layers upon friction behavior of organized molecular films of comb-polymers containing fluorocarbon chains [J].
Fujimori, A ;
Araki, T ;
Nakahara, H .
CHEMISTRY LETTERS, 2000, (08) :898-899
[6]   Polymorphism of acrylic and methacrylic acid esters containing long fluorocarbon chains and their polymerizability [J].
Fujimori, A ;
Saitoh, H ;
Shibasaki, Y .
JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY, 1999, 57 (03) :631-642
[7]   Formation of the newly greenish organized molecular film of long-chain diynoic acid derivatives by photopolymerization and its structural study using near-edge X-ray absorption fine structure (NEXAFS) spectroscopy [J].
Fujimori, A ;
Ishitsuka, M ;
Nakahara, H ;
Ito, E ;
Hara, M ;
Kanai, K ;
Ouchi, Y ;
Seki, K .
JOURNAL OF PHYSICAL CHEMISTRY B, 2004, 108 (35) :13153-13162
[8]   Characteristics of monolayer behavior and multilayer film structures of comb polymers having different kinds of fluorocarbon side-chains [J].
Fujimori, A ;
Nakahara, H ;
Ito, E ;
Hara, M ;
Kanai, K ;
Ouchi, Y ;
Seki, K .
JOURNAL OF COLLOID AND INTERFACE SCIENCE, 2004, 278 (01) :184-191
[9]   Changes in the near-edge X-ray absorption fine structure spectra of long-chain diacetylene derivatives through photopolymerization in Langmuir-Blodgett films [J].
Fujimori, A ;
Ishitsuka, M ;
Nakahara, H ;
Ito, E ;
Hara, M ;
Kanai, K ;
Ishii, H ;
Ouchi, Y ;
Seki, K .
JOURNAL OF POLYMER SCIENCE PART B-POLYMER PHYSICS, 2004, 42 (12) :2329-2336
[10]   Change of molecular packing and orientation from monolayer to multilayers of hydrogenated and fluorinated carboxylates studied by in-plane X-ray diffraction together with NEXAFS spectroscopy at CK-edge [J].
Fujimori, A ;
Sugita, Y ;
Nakahara, H ;
Ito, E ;
Hara, M ;
Matsuie, N ;
Kanai, K ;
Ouchi, Y ;
Seki, K .
CHEMICAL PHYSICS LETTERS, 2004, 387 (4-6) :345-351