Cathodic reactivity of graphite with carbon dioxide: an efficient formation of carboxylated carbon materials

被引：25
作者：
Dano, C [1 ]
Simonet, J [1 ]
机构：
[1] Univ Rennes 1, Lab Electrochim Mol & Macromol, UMR 6510, F-35042 Rennes, France
来源：
JOURNAL OF ELECTROANALYTICAL CHEMISTRY | 2004年 / 564卷 / 1-2期
关键词：
graphite; cathodic charge; graphite carboxylation; carbon modification; tetraalkylammonium salt;
D O I：
10.1016/j.jelechem.2003.10.012
中图分类号：
O65 [分析化学];
学科分类号：
070302 ; 081704 ;
摘要：
Several kinds of graphites (natural from Ceylon, highly oriented pyrolytic (HOPG), pyrolytic crystals) were cathodically charged in the presence of dimethylformamide containing 0.1 M tetraalkylammonium tetrafluoroborate. After uptake of different amounts of charge, the reduced materials were allowed to react with carbon dioxide in solution. Data on the rate of carboxylation are given and the analytical methods providing information on the modification of graphite on the surface and in the bulk. (C) 2003 Elsevier B.V. All rights reserved.
引用
收藏
页码：115 / 121
页数：7
相关论文
共 24 条
  • [1] TETRA-ALKYLAMMONIUM-GRAPHITE LAMELLAR COMPOUNDS - A NEW CLASS OF REDUCING REAGENTS IN ORGANIC-CHEMISTRY
    BERTHELOT, J
    JUBAULT, M
    SIMONET, J
    [J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1982, (13) : 759 - 760
  • [2] BESENHAR.J, 1971, Z NATURFORSCH PT B, VB 26, P1225
  • [3] STAGE-WISE OXIDATION OF GRAPHITE IN NON-AQUEOUS, NEUTRAL ELECTROLYTES
    BESENHARD, J
    FRITZ, HP
    [J]. ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES, 1972, B 27 (11): : 1294 - 1298
  • [4] THE ELECTROCHEMISTRY OF BLACK CARBONS
    BESENHARD, JO
    FRITZ, HP
    [J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1983, 22 (12): : 950 - 975
  • [5] ELECTROCHEMICAL PREPARATION AND PROPERTIES OF IONIC ALKALI METAL- AND NR4-GRAPHITE INTERCALATION COMPOUNDS IN ORGANIC ELECTROLYTES
    BESENHARD, JO
    [J]. CARBON, 1976, 14 (02) : 111 - 115
  • [6] Revisited structures of dense and dilute stage II lithium-graphite intercalation compounds
    Billaud, D
    Henry, FX
    Lelaurain, M
    Willmann, P
    [J]. JOURNAL OF PHYSICS AND CHEMISTRY OF SOLIDS, 1996, 57 (6-8) : 775 - 781
  • [7] ELECTROCHEMICAL PREPARATION OF SALTS FROM WELL-ORIENTED GRAPHITE
    BOTTOMLEY, M
    UBBELOHDE, AR
    PARRY, GS
    YOUNG, DA
    [J]. JOURNAL OF THE CHEMICAL SOCIETY, 1963, (DEC): : 5674 - &
  • [8] Electroreductive coating of electrodes from soluble polypyrrole-ruthenium (II) complexes: ion modulation effects on their electroactivity
    Deronzier, A
    Eloy, D
    Jardon, P
    Martre, A
    Moutet, JC
    [J]. JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1998, 453 (1-2) : 179 - 185
  • [9] Cyclic voltammetry and XPS analyses of graphite felt derivatized by non-Kolbe reactions in aqueous media
    Geneste, F
    Cadoret, M
    Moinet, C
    Jezequel, G
    [J]. NEW JOURNAL OF CHEMISTRY, 2002, 26 (09) : 1261 - 1266
  • [10] First covalent attachment of a polypyridyl ruthenium complex on a graphite felt electrode
    Geneste, F
    Moinet, C
    Jezequel, G
    [J]. NEW JOURNAL OF CHEMISTRY, 2002, 26 (11) : 1539 - 1541
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