Tuning acceptor energy level for efficient charge collection in copper-phthalocyanine-based organic solar cells

被引:107
作者
Chu, CW [1 ]
Shrotriya, V [1 ]
Li, G [1 ]
Yang, Y [1 ]
机构
[1] Univ Calif Los Angeles, Dept Mat Sci & Engn, Los Angeles, CA 90095 USA
关键词
D O I
10.1063/1.2194207
中图分类号
O59 [应用物理学];
学科分类号
摘要
We compare organic donor/acceptor heterojunction photovoltaic devices based on copper phthalocyanine (CuPc) as the donor and [6,6]-phenyl C-60 butyric acid methyl ester (PCBM) or buckminsterfullerene (C-60) as the acceptor. The effect of the two acceptors on open-circuit voltage and short-circuit current density is studied. Improved interface properties, optimal energy level matching, and more balanced charge transport are believed to be the reasons for better performance of CuPc/PCBM heterojunction device, in terms of photocurrent and fill factor. The energy conversion efficiency of the devices under AM1.5G solar illumination at 130 mW/cm(2) is improved to 1.18%, up from 0.74%.
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页数:3
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