Breaking the Fischer-Tropsch synthesis selectivity: direct conversion of syngas to gasoline over hierarchical Co/H-ZSM-5 catalysts

被引：107
作者：
Sartipi, Sina [1 ]
Parashar, Kshitij [1 ]
Makkee, Michiel [1 ]
Gascon, Jorge [1 ]
Kapteijn, Freek [1 ]
机构：
[1] Delft Univ Technol, Dept Chem Engn, NL-2628 BL Delft, Netherlands
来源：
CATALYSIS SCIENCE & TECHNOLOGY | 2013年 / 3卷 / 03期
关键词：
SUPPORTED RUTHENIUM NANOPARTICLES; SECONDARY REACTIONS; SYNTHESIS GAS; COBALT; DIFFUSION; HYDROCRACKING; ISOPARAFFINS; ZEOLITES;
D O I：
10.1039/c2cy20744c
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
We report the combination of Fischer-Tropsch catalyst with acid functionality in one single catalyst particle. The resulting bifunctional catalyst is capable of producing gasoline range hydrocarbons from synthesis gas in one catalytic step with outstanding activities and selectivities.
引用
收藏
页码：572 / 575
页数：4
相关论文
共 32 条
  • [1] Mesoporous ZSM-5 zeolite catalysts prepared by desilication with organic hydroxides and comparison with NaOH leaching
    Abello, Sonia
    Bonilla, Adriana
    Perez-Ramirez, Javier
    [J]. APPLIED CATALYSIS A-GENERAL, 2009, 364 (1-2) : 191 - 198
  • [2] A core/shell catalyst produces a spatially confined effect and shape selectivity in a consecutive reaction
    Bao, Jun
    He, Jingjiang
    Zhang, Yi
    Yoneyama, Yoshiharu
    Tsubaki, Noritatsu
    [J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2008, 47 (02) : 353 - 356
  • [3] Cobalt particle size effects in the Fischer-Tropsch reaction studied with carbon nanofiber supported catalysts
    Bezemer, GL
    Bitter, JH
    Kuipers, HPCE
    Oosterbeek, H
    Holewijn, JE
    Xu, XD
    Kapteijn, F
    van Dillen, AJ
    de Jong, KP
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2006, 128 (12) : 3956 - 3964
  • [4] Fischer-Tropsch Waxes Upgrading via Hydrocracking and Selective Hydroisomerization
    Bouchy, C.
    Hastoy, G.
    Guillon, E.
    Martens, J. A.
    [J]. OIL & GAS SCIENCE AND TECHNOLOGY-REVUE D IFP ENERGIES NOUVELLES, 2009, 64 (01): : 91 - 112
  • [5] Mesoporous Beta Zeolite-Supported Ruthenium Nanoparticles for Selective Conversion of Synthesis Gas to C5-C11 Isoparaffins
    Cheng, Kang
    Kang, Jincan
    Huang, Shuiwang
    You, Zhenya
    Zhang, Qinghong
    Ding, Jiansheng
    Hua, Weiqi
    Lou, Yinchuan
    Deng, Weiping
    Wang, Ye
    [J]. ACS CATALYSIS, 2012, 2 (03): : 441 - 449
  • [6] Effect of the Mesostructuration of the Beta Zeolite Support on the Properties of Cobalt Catalysts for Fischer-Tropsch Synthesis
    Costa Pereira, Amalia Luz
    Maria Gonzalez-Carballo, Juan
    Jose Perez-Alonso, Francisco
    Rojas, Sergio
    Garcia Fierro, Jose Luis
    Rangel, Maria do Carmo
    [J]. TOPICS IN CATALYSIS, 2011, 54 (1-4) : 179 - 189
  • [7] Zeolite Y Crystals with Trimodal Porosity as Ideal Hydrocracking Catalysts
    de Jong, Krijn P.
    Zecevic, Jovana
    Friedrich, Heiner
    de Jongh, Petra E.
    Bulut, Metin
    van Donk, Sander
    Kenmogne, Regine
    Finiels, Annie
    Hulea, Vasile
    Fajula, Francois
    [J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2010, 49 (52) : 10074 - 10078
  • [8] DeKlerk A, 2010, RSC CATAL SER, P1
  • [9] On the Origin of the Cobalt Particle Size Effects in Fischer-Tropsch Catalysis
    den Breejen, J. P.
    Radstake, P. B.
    Bezemer, G. L.
    Bitter, J. H.
    Froseth, V.
    Holmen, A.
    de Jong, K. P.
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2009, 131 (20) : 7197 - 7203
  • [10] Deshmukh SR, 2011, BIOFUELS-UK, V2, P315, DOI [10.4155/bfs.11.17, 10.4155/BFS.11.17]
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