Lithium-oxygen batteries: At a crossroads?

被引：28

作者：

Vegge, Tejs ^{[1
]}

Garcia-Lastra, Juan Maria ^{[1
]}

Siegel, Donald J. ^{[2
,3
]}

机构：

[1] Tech Univ Denmark, Dept Energy Convers & Storage, Lyngby, Denmark

[2] Univ Michigan, Mech Engn Mat Sci & Engn, Appl Phys Program, Energy Inst, Ann Arbor, MI 48109 USA

[3] Univ Michigan, JCESR, Ann Arbor, MI 48109 USA

来源：

CURRENT OPINION IN ELECTROCHEMISTRY | 2017年 / 6卷 / 01期

基金：

美国国家科学基金会;

关键词：

CHARGE-TRANSPORT; IONIC LIQUID; LI-O-2; BATTERIES; ELECTROCHEMICAL IMPEDANCE; ELECTRONIC-STRUCTURE; REACTION-MECHANISMS; SODIUM SUPEROXIDE; LAYERED OXIDES; AIR BATTERIES; ELECTROLYTES;

D O I：

10.1016/j.coelec.2017.10.014

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

In this current opinion, we critically review and discuss some of the most important recent findings in the field of rechargeable lithium-oxygen batteries. We discuss recent discoveries like the evolution of reactive singlet oxygen and the use of organic additives to bypass reactive LiO2 reaction intermediates, and their possible implications on the potential for commercialization of lithium-oxygen batteries. Finally, we perform a critical assessment of lithium-superoxide batteries and the reversibility of lithium-hydroxide batteries.

引用

页码：100 / 107

页数：8

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