Ordered mesoporous metal oxides: synthesis and applications

被引:709
作者
Ren, Yu [2 ,3 ,4 ]
Ma, Zhen [1 ]
Bruce, Peter G. [3 ,4 ]
机构
[1] Fudan Univ, Dept Environm Sci & Engn, Shanghai 200433, Peoples R China
[2] NICE, Beijing 102209, Peoples R China
[3] Univ St Andrews, Sch Chem, St Andrews KY16 9ST, Fife, Scotland
[4] Univ St Andrews, EaStChem, St Andrews KY16 9ST, Fife, Scotland
基金
英国工程与自然科学研究理事会; 中国国家自然科学基金;
关键词
HIGH-SURFACE-AREA; GAS-SENSING PROPERTIES; SINGLE-CRYSTAL CR2O3; TIO2; SOLAR-CELLS; MOLECULAR-SIEVES; TANTALUM OXIDE; PHOTOCATALYTIC ACTIVITY; NANOCASTED SYNTHESIS; FRAMEWORK STRUCTURE; POSITIVE ELECTRODE;
D O I
10.1039/c2cs35086f
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Great progress has been made in the preparation and application of ordered mesoporous metal oxides during the past decade. However, the applications of these novel and interesting materials have not been reviewed comprehensively in the literature. In the current review we first describe different methods for the preparation of ordered mesoporous metal oxides; we then review their applications in energy conversion and storage, catalysis, sensing, adsorption and separation. The correlations between the textural properties of ordered mesoporous metal oxides and their specific performance are highlighted in different examples, including the rate of Li intercalation, sensing, and the magnetic properties. These results demonstrate that the mesoporosity has a direct impact on the properties and potential applications of such materials. Although the scope of the current review is limited to ordered mesoporous metal oxides, we believe that the information may be useful for those working in a number of fields.
引用
收藏
页码:4909 / 4927
页数:19
相关论文
共 241 条
[1]   Metal oxide photoanodes for solar hydrogen production [J].
Alexander, Bruce D. ;
Kulesza, Pawel J. ;
Rutkowska, Iwona ;
Solarska, Renata ;
Augustynski, Jan .
JOURNAL OF MATERIALS CHEMISTRY, 2008, 18 (20) :2298-2303
[2]   Synthesis of macro-mesoporous niobium oxide molecular sieves by a ligand-assisted vesicle templating strategy [J].
Antonelli, DM .
MICROPOROUS AND MESOPOROUS MATERIALS, 1999, 33 (1-3) :209-214
[3]   SYNTHESIS OF HEXAGONALLY PACKED MESOPOROUS TIO2 BY A MODIFIED SOL-GEL METHOD [J].
ANTONELLI, DM ;
YING, JY .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1995, 34 (18) :2014-2017
[4]  
Antonelli DM, 1999, ADV MATER, V11, P487, DOI 10.1002/(SICI)1521-4095(199904)11:6<487::AID-ADMA487>3.0.CO
[5]  
2-2
[6]   Mesoporous materials [J].
Antonelli, DM ;
Ying, JY .
CURRENT OPINION IN COLLOID & INTERFACE SCIENCE, 1996, 1 (04) :523-529
[7]   Ligand-assisted liquid crystal templating in mesoporous niobium oxide molecular sieves [J].
Antonelli, DM ;
Nakahira, A ;
Ying, JY .
INORGANIC CHEMISTRY, 1996, 35 (11) :3126-3136
[8]   Lithium aluminum manganese oxide having spinel-framework structure for long-life lithium-ion batteries [J].
Ariyoshi, Kingo ;
Iwata, Eiichi ;
Kuniyoshi, Minoru ;
Wakabayashi, Hiromichi ;
Ohzuku, Tsutomu .
ELECTROCHEMICAL AND SOLID STATE LETTERS, 2006, 9 (12) :A557-A560
[9]   Nanocasting of Ordered Mesoporous Co3O4-Based Polyoxometalate Composite Frameworks [J].
Armatas, Gerasimos S. ;
Katsoulidis, Alexandros P. ;
Petrakis, Dimitris E. ;
Pomonis, Philippos J. ;
Kanatzidis, Mercouri G. .
CHEMISTRY OF MATERIALS, 2010, 22 (20) :5739-5746
[10]   Synthesis and acidic catalytic properties of ordered mesoporous alumina-tungstophosphoric acid composites [J].
Armatas, Gerasimos S. ;
Katsoulidis, Alexandros P. ;
Petrakis, Dimitris E. ;
Pomonis, Philippos J. .
JOURNAL OF MATERIALS CHEMISTRY, 2010, 20 (39) :8631-8638