A highly sensitive gas sensor based on Pd-doped Fe3O4 nanoparticles for volatile organic compounds detection

被引：41

作者：

Zhai, Qingfeng ^{[1
]}

Du, Bin ^{[1
,2
]}

Feng, Rui ^{[1
]}

Xu, Weiying ^{[1
]}

Wei, Qin ^{[2
]}

机构：

[1] Univ Jinan, Sch Resources & Environm Sci, Jinan 250022, Peoples R China

[2] Univ Jinan, Sch Chem & Chem Engn, Key Lab Chem Sensing & Anal Univ Shandong, Jinan 250022, Peoples R China

来源：

ANALYTICAL METHODS | 2014年 / 6卷 / 03期

关键词：

SENSING PROPERTIES; SNO2; NANOWIRES; MICROSPHERES; METAL; NANOCRYSTALS; PERFORMANCE; NANOTUBES; NANORODS; FILMS;

D O I：

10.1039/c3ay41867g

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

Novel sensing materials, Pd-supported Fe3O4 nanoparticles (Pd@Fe3O4), were successfully prepared and characterized by X-ray diffraction (XRD), energy dispersive X-ray spectroscopy (EDS), scanning electron microscopy (SEM) and high-resolution transmission electron microscopy (HRTEM) in this study. The gas sensing properties of the Pd@Fe3O4 nanoparticles were systematically investigated. The results showed that the doped Pd could significantly enhance the gas sensing characteristics of Fe3O4. The Pd@Fe3O4 nanoparticles present high sensitivity to diverse volatile organic compounds (VOCs), such as methanol, ethanol, propanol, acetone, etc. The response and recovery time towards 40 ppm of ethanol at 300 degrees C were 18 s and 30 s, respectively. The enhanced sensor performance was attributed to the catalytic properties of Pd nanoparticles, and a possible mechanism was proposed.

引用

页码：886 / 892

页数：7

共 48 条

[1] Metal supported on dendronized magnetic nanoparticles: Highly selective hydroformylation catalysts [J].

Abu-Reziq, R ;

Alper, H ;

Wang, DS ;

Post, ML .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2006, 128 (15) :5279-5282

[2] Facile Microwave-Assisted Synthesis and Magnetic and Gas Sensing Properties of Fe3O4 Nanoroses [J].

Ai, Zhihui ;

Deng, Kejian ;

Wan, Qianfen ;

Zhang, Lizhi ;

Lee, Shuncheng .

JOURNAL OF PHYSICAL CHEMISTRY C, 2010, 114 (14) :6237-6242

[3] Nanowires Assembled SnO2 Nanopolyhedrons with Enhanced Gas Sensing Properties [J].

Chen, Di ;

Xu, Jing ;

Xie, Zhong ;

Shen, Guozhen .

ACS APPLIED MATERIALS & INTERFACES, 2011, 3 (06) :2112-2117

[4] Fast response H2S gas sensing characteristics with ultra-thin CuO islands on sputtered SnO2 [J].

Chowdhuri, A ;

Gupta, V ;

Sreenivas, K .

SENSORS AND ACTUATORS B-CHEMICAL, 2003, 93 (1-3) :572-579

[5] Metal and metal oxide nanoparticles in chemiresistors: Does the nanoscale matter? [J].

Franke, ME ;

Koplin, TJ ;

Simon, U .

SMALL, 2006, 2 (01) :36-50

[6] Monodisperse mesoporous superparamagnetic single-crystal magnetite nanoparticles for drug delivery [J].

Guo, Shaojun ;

Li, Dan ;

Zhang, Lime ;

Li, Jing ;

Wang, Erkang .

BIOMATERIALS, 2009, 30 (10) :1881-1889

[7] In situ and operando spectroscopy for assessing mechanisms of gas sensing [J].

Gurlo, Alexander ;

Riedel, Ralf .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2007, 46 (21) :3826-3848

[8] Visible-Light-Assisted HCHO Gas Sensing Based on Fe-Doped Flowerlike ZnO at Room Temperature [J].

Han, Lina ;

Wang, DeJun ;

Lu, Yongchun ;

Jiang, Tengfei ;

Liu, Bingkun ;

Lin, Yanhong .

JOURNAL OF PHYSICAL CHEMISTRY C, 2011, 115 (46) :22939-22944

[9] Meso- and Macroporous Co3O4 Nanorods for Effective VOC Gas Sensors [J].

Hoa Nguyen ;

El-Safty, Sherif A. .

JOURNAL OF PHYSICAL CHEMISTRY C, 2011, 115 (17) :8466-8474

[10] A NOVEL STRUCTURE FOR DETECTING ORGANIC VAPORS AND HYDROCARBONS BASED ON A PD-MOS SENSOR [J].

HORNIK, W .

SENSORS AND ACTUATORS B-CHEMICAL, 1990, 1 (1-6) :35-39

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