Synthesis and spectral parameters of tetra(6-tert-butyl-2,3-quinoxalino)porphyrazine and its metal complexes

被引：5

作者：

Efimova, S. V. ^{[1
]}

Korzhenevskii, A. B. ^{[2
]}

Koifman, O. I. ^{[2
]}

机构：

[1] Ivanovo State Univ Chem Technol, Ivanovo 153000, Russia

[2] Russian Acad Sci, Inst Solut Chem, Ivanovo, Russia

来源：

RUSSIAN JOURNAL OF GENERAL CHEMISTRY | 2008年 / 78卷 / 07期

关键词：

General Chemistry; Phthalocyanine; Spectral Parameter; Electronic Absorption Spectrum; Cobalt Complex;

D O I：

10.1134/S1070363208070293

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Tetra(6-tert-butyl-2,3-quinoxalino)porphyrazine and its complexes with bivalent metals were synthesized for the first time by template tetramerization of 6-tert-butylquinoxaline-2,3-dicarbonitrile. The obtained macrocyclic compounds are soluble in hydrophobic solvents. Their electronic absorption spectra in organic solvents and the spectra of the corresponding protonated forms in sulfuric acid were studied.

引用

页码：1447 / 1451

页数：5

共 8 条

[1]

GALPERIN MG, 1972, KHIM GETEROTSIKL+, P858

[2]

GALPERN EG, 1973, B ACAD SCI USSR CH+, P1976

[3]

Galpern M. G., 1969, ZH OBSHCH KHIM, V39, P2536

[4]

GALPERN MG, 1974, THESIS MOSCOW

[5]

GELZER C, 1887, CHEM BER, V20, P3253

[6] Azaanalogs of phthalocyanine: Syntheses and properties [J].

Kudrevich, SV ;

vanLier, JE .

COORDINATION CHEMISTRY REVIEWS, 1996, 156 :163-182

[7]

LUKYANETS EA, 1971, ZH OBSHCH KHIM+, V41, P934

[8] HYDROGEN-CYANIDE CHEMISTRY .3. SYNTHESIS OF DIIMINOSUCCINONITRILE AND ITS CONVERSION TO DIAMINOMALEONITRILE [J].

WEBSTER, OW ;

HARTTER, DR ;

BEGLAND, RW ;

SHEPPARD, WA ;

CAIRNCRO.A .

JOURNAL OF ORGANIC CHEMISTRY, 1972, 37 (25) :4133-4136

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