Fabrication of Homogenous Polymer-Zeolite Nanocomposites as Mixed-Matrix Membranes for Gas Separation

被引：32
|
作者：
Karkhanechi, Hamed [2 ]
Kazemian, Hossein [1 ]
Nazockdast, Hossein [3 ]
Mozdianfard, Mohammad R. [4 ]
Bidoki, Seyed M. [2 ]
机构：
[1] Western Univ, Dept Chem & Biochem Engn, London, ON N6A 5B9, Canada
[2] Univ Yazd, Dept Engn, Yazd, Iran
[3] Amir Kabir Univ Technol, Dept Polymer Engn, Tehran, Iran
[4] Univ Kashan, Dept Chem Engn, Kashan, Iran
来源：
CHEMICAL ENGINEERING & TECHNOLOGY | 2012年 / 35卷 / 05期
关键词：
Gas separation; Mixed-matrix membranes; Nano-zeolite; Nanocomposite; Polyimide; CHAIN RIGIDIFICATION; POLYIMIDE MEMBRANE; CARBON-DIOXIDE; PORE BLOCKAGE; PERMEATION; TEMPLATE; SIZE;
D O I：
10.1002/ceat.201100236
中图分类号：
TQ [化学工业];
学科分类号：
0817 ;
摘要：
Interfacial void-free mixed-matrix membranes (MMMs) of polyimide (PI)/zeolite were developed using 13X and Linde type?A nano-zeolites and tested for gas separation purposes. Fabrication of a void-free polymer-zeolite interface was verified by the decreasing permeability developed by the MMMs for the examined gases, in comparison to the pure PI membrane. The molecular sieving effect introduced by zeolite?13X improved the CO2/N2 and CO2/CH4 selectivity of the MMMs. Separation tests indicated that the manufactured nanocomposite membrane with 30?% loading of 13X had the highest permselectivity for the gas pairs CO2/CH4 and CO2/N2 at the three examined feed pressures of 4, 8 and 12?atm.
引用
收藏
页码：885 / 892
页数：8
相关论文
共 50 条
  • [41] Development of a mechanistic model for mass transfer in sorption selective mixed-matrix membranes for gas separation
    Kramer, V.
    Huelague, D.
    Kraume, M.
    Lyagin, E.
    EUROMEMBRANE CONFERENCE 2012, 2012, 44 : 1867 - 1869
  • [42] Carbon nanotube-based mixed-matrix membranes with supramolecularly engineered interface for enhanced gas separation performance
    Zhang, Qinnan
    Li, Si
    Wang, Ceming
    Chang, Hsueh-Chia
    Guo, Ruilan
    JOURNAL OF MEMBRANE SCIENCE, 2020, 598
  • [43] Fabrication of mixed-matrix membranes with MOF-derived porous carbon for CO2 separation
    Zhang, Weixin
    Liu, Dahuan
    Guo, Xiangyu
    Huang, Hongliang
    Zhong, Chongli
    AICHE JOURNAL, 2018, 64 (09) : 3400 - 3409
  • [44] Highly Plasticization-Resistant Tro<spacing diaeresis>ger's base Polymer-MOF Mixed-Matrix membranes for stable gas separation
    Lee, Jieun
    Jeon, Seungbae
    An, Eun Ji
    Kim, Hyung Gwon
    Jo, Jin Hui
    Han, Nara
    Park, Sungmin
    Chi, Won Seok
    SEPARATION AND PURIFICATION TECHNOLOGY, 2025, 356
  • [45] Scalable Fabrications of Mixed-Matrix Membranes via Polymer Modification-Enabled In Situ Metal-Organic Framework Formation for Gas Separation: A Review
    Park, Sunghwan
    Lee, Young-Sei
    APPLIED CHEMISTRY FOR ENGINEERING, 2023, 34 (03): : 213 - 220
  • [46] Gas Permeation Models in Mixed Matrix Membranes for Gas Separation
    Rafiq, Sikander
    Maulud, Abdulhalim
    Man, Zakaria
    Muhammad, Nawshad
    PROCEEDINGS OF THE INTERNATIONAL CONFERENCE ON PROCESS ENGINEERING AND ADVANCED MATERIALS 2012-ICPEAM 2012, 2014, 917 : 317 - 324
  • [47] Development of 3D-printed polymer-zeolite composite monoliths for gas separation
    Thakkar, Harshul
    Lawson, Shane
    Rownaghi, Ali A.
    Rezaei, Fateme
    CHEMICAL ENGINEERING JOURNAL, 2018, 348 : 109 - 116
  • [48] Development and Characterization of Defect-Free Matrimid® Mixed-Matrix Membranes Containing Activated Carbon Particles for Gas Separation
    Weigelt, Fynn
    Georgopanos, Prokopios
    Shishatskiy, Sergey
    Filiz, Volkan
    Brinkmann, Torsten
    Abetz, Volker
    POLYMERS, 2018, 10 (01)
  • [49] Perfluoropolymer/Molecular Sieve Mixed-Matrix Membranes
    Golemme, Gianni
    Santaniello, Anna
    MEMBRANES, 2019, 9 (02)
  • [50] MOF/Polymer Mixed-Matrix Membranes Preparation: Effect of Main Synthesis Parameters on CO2/CH4 Separation Performance
    Kulak, Harun
    Thur, Raymond
    Vankelecom, Ivo F. J.
    MEMBRANES, 2022, 12 (04)
12345