Effects of a Steam Pre-treatment on the Formation and Transformation of Alumina Phases on Fe Aluminide Coatings

被引:12
作者
Aguero, A. [1 ]
Hernandez, M. [1 ]
Santaballa, A. [1 ]
机构
[1] INTA, Area Mat Met, Madrid 28850, Spain
来源
OXIDATION OF METALS | 2013年 / 79卷 / 5-6期
关键词
Alumina scale transformation; Fe aluminide coatings; High temperature oxidation; Steam pre-treatment; WATER-VAPOR; OXIDATION BEHAVIOR;
D O I
10.1007/s11085-012-9351-1
中图分类号
TF [冶金工业];
学科分类号
0806 ;
摘要
Several researchers have studied the transformation of metastable aluminas (gamma- and theta-) to alpha-Al2O3 but very little is known regarding alumina scales formed under water vapour and their transformation to alpha-Al2O3. Some results have indicated that water vapour increases the oxidation rate of alumina-scale forming coatings but others have found the opposite, that is, that under water vapour the oxidation rates decrease as either transition aluminas do not form or the transformation to alpha-Al2O3 is accelerated. In addition, it was found that chi-Al2O3 is the only oxide that forms at the initial stages of oxidation under 100 % steam on Fe-Al coatings at 650 A degrees C. Under these conditions, this oxide is very protective, and slowly transforms onto alpha-Al2O3. A preliminary study of the transformation of chi- to alpha-Al2O3 at 900 A degrees C under laboratory air was carried out. chi-Al2O3 was generated by a steam pre-treatment on slurry Fe aluminide coatings deposited on P92.
引用
收藏
页码:601 / 611
页数:11
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