Cd(II) and Zn(II) Coordination Polymers Assembled from Benzoyltrifluoroacetone and 1,2-Bis(4-Pyridyl)Ethane Ancillary ligands

被引：0
作者：
Marandi, Farzin [1 ]
Teimouri, Shabahang [1 ]
Fun, Hoong-Kun [2 ,3 ]
机构：
[1] Payame Noor Univ, Dept Chem, Tehran 193953697, Iran
[2] Univ Sains Malaysia, Xray Crystallog Unit, Sch Phys, Usm 11800, Penang, Malaysia
[3] King Saud Univ, Dept Pharmaceut Chem, Coll Pharm, Riyadh 11451, Saudi Arabia
来源：
ACTA CHIMICA SLOVENICA | 2013年 / 60卷 / 02期
关键词：
Coordination polymers; beta-Diketone; 1,2-Bis(4-pyridyl)ethane; METAL-ORGANIC FRAMEWORK; DOT-PI-INTERACTIONS; CRYSTAL-STRUCTURES; LEAD(II) COMPLEXES; CATALYTIC-ACTIVITY; CADMIUM COMPLEXES; HYDROGEN-BONDS; AG-I; SORPTION; OXIDATION;
D O I：
暂无
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Two novel cadmium(II) and zinc(II) metal-organic coordination polymers with a beta-diketone and N-donor ancillary ligands, [Cd(bpe)(btfa)(2)](n) (1) and [Zn(bpe)(btfa)(2)](n) (2), (Hbtfa = benzoyltrifluoroacetone and bpe = 1,2-bis(4-pyridyl)ethane), have been prepared and characterized by elemental analysis, IR and H-1 NMR spectroscopy, and studied by thermal gravimetric analysis as well as single crystal X-ray diffraction. The crystal and molecular structures of 1 and 2 have been solved by X-ray diffraction and they turned out to be one-dimensional polymers with zigzag (1) and linear (2) dispositions of the metal atoms. These one-dimensional polymers are further connected to form a 3D supramolecular network by C-H center dot center dot center dot O and C-H center dot center dot center dot F interactions. Thermal stabilities of these polymeric complexes have also been investigated.
引用
收藏
页码：328 / 334
页数：7
相关论文
共 57 条
[1]   3d-4f Combined Chemistry: Synthetic Strategies and Magnetic Properties [J].
Andruh, Marius ;
Costes, Jean-Pierre ;
Diaz, Carmen ;
Gao, Song .
INORGANIC CHEMISTRY, 2009, 48 (08) :3342-3359
[2]   Polymethylene spacer regulated structural divergence in cadmium complexes: Unusual trigonal prismatic and severely distorted octahedral coordination [J].
Banerjee, S ;
Ghosh, A ;
Wu, B ;
Lassahn, PG ;
Janiak, C .
POLYHEDRON, 2005, 24 (05) :593-599
[3]   Synthesis, structure and bonding of cadmium(II) thiocyanate systems featuring nitrogen based ligands of different denticity [J].
Banerjee, S ;
Wu, B ;
Lassahn, PG ;
Janiak, C ;
Ghosh, A .
INORGANICA CHIMICA ACTA, 2005, 358 (03) :535-544
[4]   Coordination complexes exhibiting anion ••• π interactions:: Synthesis, structure, and theoretical studies [J].
Barrios, Leoni A. ;
Aromi, Guillem ;
Frontera, Antonio ;
Quinonero, David ;
Deya, Pere M. ;
Gamez, Patrick ;
Roubeau, Olivier ;
Shotton, Elizabeth J. ;
Teat, Simon J. .
INORGANIC CHEMISTRY, 2008, 47 (13) :5873-5881
[5]   3-D Lanthanide Metal-Organic Frameworks: Structure, Photoluminescence, and Magnetism [J].
Black, Cory A. ;
Costa, Jose Sanchez ;
Fu, Wen Tian ;
Massera, Chiara ;
Roubeau, Olivier ;
Teat, Simon J. ;
Aromi, Guillem ;
Gamez, Patrick ;
Reedijk, Jan .
INORGANIC CHEMISTRY, 2009, 48 (03) :1062-1068
[6]  
*BRUK AXS INC, 2005, APEX2 VERS 1 27 SAIN
[7]  
Bureekaew S, 2009, NAT MATER, V8, P831, DOI [10.1038/NMAT2526, 10.1038/nmat2526]
[8]   Rationally designed micropores within a metal-organic framework for selective sorption of gas molecules [J].
Chen, Banglin ;
Ma, Shengqian ;
Zapata, Fatima ;
Fronczek, Frank R. ;
Lobkovsky, Emil B. ;
Zhou, Hong-Cai .
INORGANIC CHEMISTRY, 2007, 46 (04) :1233-1236
[9]   A Luminescent Metal-Organic Framework with Lewis Basic Pyridyl Sites for the Sensing of Metal Ions [J].
Chen, Banglin ;
Wang, Liangbo ;
Xiao, Yunqing ;
Fronczek, Frank R. ;
Xue, Ming ;
Cui, Yuanjing ;
Qian, Guodong .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2009, 48 (03) :500-503
[10]  
Chopra D., 2006, CRYST GROWTH DES, V6, P1035
123456