Formation of a new 1D coordination polymer by in situ ligand reaction of 2,4,6-tris(pyrazol-1-yl)-1,3,5-s-triazine

被引：0

作者：

Cao, Qiang ^{[1
]}

机构：

[1] Weinan Normal Univ, Coll Chem & Life Sci, Weinan 714000, Shaanxi, Peoples R China

来源：

JOURNAL OF CHEMICAL RESEARCH | 2012年 / 11期

关键词：

in situ ligand reaction; benzenedicarboxylic acid; crystal structure; 2,4,6-trismethoxy-1,3,5-triazine; METAL-ORGANIC FRAMEWORK; COMPLEXES; SORPTION;

D O I：

10.3184/174751912X13469466943350

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Solvothermal reactions of Zn(NO3)(2)center dot 6H(2)O, 1,4-benzenedicarboxylic acid (H2BDC) and 2,4,6-tris(pyrazol-1-yl)-1,3,5-s-triazine, yielded a new coordination polymer [Zn(BDC)(pz)center dot H2O](n) (pz= pyrazole). The in situ methanolysis reaction of 2,4,6-tris(pyrazol-1-yl)-1,3,5-s-triazine with pyrazole and 2,4,6-trismethoxy-1,3,5-triazine was confirmed by their single-crystal structures. [Zn(BDC)(pz)center dot H2O](n) was characterised by elemental analysis, IR, powder X-ray diffraction, photoluminescence and thermogravimetric analyses.

引用

页码：648 / 651

页数：4

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