Densities and viscosities for the binary mixtures (2-methyl-1-chloropropane plus isomeric butanol) at 298.15 and 313.15 K

被引:5
作者
Infante, C [1 ]
Artigas, H [1 ]
Lafuente, C [1 ]
Mainar, AM [1 ]
Urieta, JS [1 ]
机构
[1] Univ Zaragoza, Fac Ciencias, Dept Quim Organ & Quim Fis, E-50009 Zaragoza, Spain
关键词
binary mixtures; butanols; 2-methyl-1-chloropropane; excess properties;
D O I
10.1080/00319100108031689
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
This paper reports excess volumes, V-E, and viscosity deviations, Delta eta, for binary mixtures of 2-methyl-1-chloropropane with an isomer of butanol at the temperatures 298.15 K and 313.15 K. These properties were obtained from density and viscosity measurements. The results are correlated by means of a Redlich-Kister type equation, and interpreted in terms of molecular interactions. The systems show positive values of V-E except in a short range of compositions for mixtures containing primary butanols (1-butanol at both temperatures and 2-methyl-1-propanol at 298.15 K), whereas Delta eta presents negative values at both temperatures over the whole composition range.
引用
收藏
页码:739 / 752
页数:14
相关论文
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