1-D arrays of Cu(I)-Schiff base maintained by fourfold phenyl embraces isolating diiodocuprate(I) anions

被引：23

作者：

Amirnasr, M ^{[1
]}

Khalaji, AD

Falvello, LR

机构：

[1] Isfahan Univ Technol, Dept Chem, Esfahan 84156 83111, Iran

[2] Univ Zaragoza, CSIC, Dept Inorgan Chem, E-50009 Zaragoza, Spain

[3] Univ Zaragoza, CSIC, Inst Ciencia Mat Aragon, E-50009 Zaragoza, Spain

来源：

INORGANICA CHIMICA ACTA | 2006年 / 359卷 / 02期

关键词：

1-D array; Schiff base; fourfold phenyl embraces; diiodocuprate(I); supramolecular motif;

D O I：

10.1016/j.ica.2005.10.036

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reaction of CuI with the bidentate Schiff base ligand (Phca(2)-dab) in acetonitrile yields a new mononuclear Cu(I) complex [Cu(Phca(2)-dab)(2)][CuI2]. The structure contains cationic moieties of Cu-I ion coordinated to four N atoms of two Phca(2)-dab ligands in a distorted tetrahedral fashion and isolated linear diiodocuprate(I) anions. The Phca(2)-dab ligand adopts a Z,Z configuration. A supramolecular motif that is a one-dimensional array of Phca(2)-dab embraces formed by the complex has been identified from the crystal packing analysis. The Phca(2)-dab embrace involves two complexes attracted by two edge-to-face (ef) interactions by the outer phenyl rings of the ligands. (c) 2005 Elsevier B.V. All rights reserved.

引用

页码：713 / 717

页数：5

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