Clean Procedure for the Synthesis of -Aminophosphonates Catalyzed by Biodegradable Ionic Liquid

被引：3

作者：

Fang, Dong ^{[1
,2
]}

Cao, Yanfang ^{[2
]}

Yang, Jinming ^{[2
]}

机构：

[1] Jiangsu Prov Key Lab Coast Wetland Bioresources &, Yancheng 224002, Jiangsu, Peoples R China

[2] Yancheng Normal Univ, Sch Chem & Chem Engn, Yancheng, Peoples R China

来源：

PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS | 2013年 / 188卷 / 07期

关键词：

-Aminophosphonates; ionic liquid; biodegradable; solvent-free; aqueous media; ONE-POT SYNTHESIS; ALPHA-AMINOPHOSPHONATES; SOLVENT-FREE; EFFICIENT CATALYST; 3-COMPONENT SYNTHESIS; PROMOTED SYNTHESIS; ACID;

D O I：

10.1080/10426507.2012.710679

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A biodegradable SO3H-functionalized ionic liquid (IL) was prepared and used as the catalyst for a one-pot, three-component condensation synthesis of -aminophosphonates from aldehydes, amines, and triethylphosphite/diethylphosphite at room temperature under solvent-free conditions or in aqueous media. The products could be simply separated from the reaction mixture and the catalyst could be recycled and reused for several times without noticeably reducing catalytic activity.

引用

页码：826 / 832

页数：7

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