A concept for bifocal contact- or intraocular lenses:: Liquid single crystal hydrogels ("-LSCH"')

被引:30
作者
Amigó-Melchior, A [1 ]
Finkelmann, H [1 ]
机构
[1] Univ Freiburg, Inst Makromol Chem, D-77103 Freiburg, Germany
关键词
liquid single crystal hydrogels; LSCH; bifocal lens;
D O I
10.1002/pat.199
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
The synthesis of liquid single crystal hydrogels ("LSCH") in suitable molds offers an innovative concept to realize bifocal contact- or intraocular-lenses. LSCH combine the properties required for applications as bifocal ophthalmic lenses: the soft and water-containing hydrogel enables oxygen permeation and exhibits high birefringence due to the liquid crystalline phase structure built up by rigid rod-like amphiphiles. Via a photo-initiated crosslinking reaction of aqueous solutions of monomeric lyotropic liquid crystalline amphiphiles in the macroscopically ordered liquid crystalline state, We obtain optically uniaxially ordered and transparent LSCH. The orientation process and the phase structure of the anisotropic hydrogel is analyzed by deuterium NMR-spectroscopy. Copyright (C) 2002 John Wiley Sons, Ltd.
引用
收藏
页码:363 / 369
页数:7
相关论文
共 8 条
[1]   BIREFRINGENT MULTIFOCAL LENSES - THEORY AND APPLICATION TO THE CORRECTION OF REFRACTIVE ERROR [J].
FIALA, W .
OPTOMETRY AND VISION SCIENCE, 1990, 67 (10) :787-791
[2]  
FIALA W, 1992, OPTOMETRY VISION SCI, V92, P329
[3]   LYOTROPIC LIQUID-CRYSTALLINE POLYMERS [J].
FINKELMANN, H ;
JAHNS, E ;
SCHAFHEUTLE, M ;
MEIER, C .
ANGEWANDTE MAKROMOLEKULARE CHEMIE, 1989, 166 :109-110
[4]   AMPHIPHILIC LIQUID-CRYSTALLINE NETWORKS - PHASE-BEHAVIOR AND ALIGNMENT BY MECHANICAL FIELDS [J].
FISCHER, P ;
SCHMIDT, C ;
FINKELMANN, H .
MACROMOLECULAR RAPID COMMUNICATIONS, 1995, 16 (06) :435-447
[5]  
Fischer P, 1998, PROG COLL POL SCI S, V111, P127
[6]  
KUPFER J, 1991, MAKROMOL CHEM-RAPID, V12, P717
[7]  
KUPFER J, 1993, THESIS FREIBURG BRSG
[8]   SHAPES OF MICELLES AND MOLECULAR-GEOMETRY SYNTHESIS AND STUDIES ON THE PHASE-BEHAVIOR, SURFACE-TENSION AND RHEOLOGY OF RIGID ROD-LIKE SURFACTANTS IN AQUEOUS-SOLUTIONS [J].
SCHAFHEUTLE, MA ;
FINKELMANN, H .
LIQUID CRYSTALS, 1988, 3 (10) :1369-1386