Homoleptic Two-Coordinate 14-Electron Palladium and Platinum Complexes with Two Bis(guanidinato)silylene Ligands

被引：10

作者：

Baus, Johannes A. ^{[1
]}

Mueck, Felix M. ^{[1
]}

Bertermann, Ruediger ^{[1
]}

Tacke, Reinhold ^{[1
]}

机构：

[1] Univ Wurzburg, Inst Anorgan Chem, D-97074 Wurzburg, Germany

来源：

EUROPEAN JOURNAL OF INORGANIC CHEMISTRY | 2016年 / 30期

关键词：

N ligands; Palladium; Platinum; Silicon; Silylenes; 6-COORDINATE SILICON(IV) COMPLEXES; DONOR-STABILIZED SILYLENES; N-HETEROCYCLIC SILYLENES; ACTIVATION; REACTIVITY; PD(0); COORDINATION; BONDS; SE; SI;

D O I：

10.1002/ejic.201600872

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The homoleptic transition-metal bis(silylene) complexes [{{iPrNC(NiPr2)NiPr}(2)Si}(2)M] (7: M = Pd; 8: M = Pt) were synthesized by treatment of [PdCl2(SMe2)(2)] and [PtCl2(PiPr(3))(2)], respectively, with the bis(guanidinato)silylene [iPrNC(NiPr2)NiPr](2)Si (2). The almost linearly coordinated Pd-0 and Pt-0 complexes 7 and 8 are two-coordinate 14-electron transition-metal species and represent unprecedented four-coordinate silicon(II) compounds with SiMN3 skeletons (M = Pd, Pt). Compound 8 is the first two-coordinate bis(silylene)platinum complex.

引用

页码：4867 / 4871

页数：5

共 40 条

[1] The transition-metal chemistry of amidinatosilylenes, -germylenes and -stannylenes [J].

Alvarez-Rodriguez, Lucia ;

Cabeza, Javier A. ;

Garcia-Alvarez, Pablo ;

Polo, Diego .

COORDINATION CHEMISTRY REVIEWS, 2015, 300 :1-28

[2]

[Anonymous], 2008, ANGEW CHEM

[3] Synthesis and characterisation of bis(amino)sllylene-nickel(0), -palladium(II), -platinum(0), -platinum(II) and copper(I) complexes [J].

Avent, AG ;

Gehrhus, B ;

Hitchcock, PB ;

Lappert, MF ;

Maciejewski, H .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2003, 686 (1-2) :321-331

[4]

Berger S., 2004, 200 and More NMR Experiments, P141

[5] N-heterocyclic silylene complexes in catalysis: new frontiers in an emerging field [J].

Blom, Burgert ;

Gallego, Daniel ;

Driess, Matthias .

INORGANIC CHEMISTRY FRONTIERS, 2014, 1 (02) :134-148

[6] New Vistas in N-Heterocyclic Silylene (NHSi) Transition-Metal Coordination Chemistry: Syntheses, Structures and Reactivity towards Activation of Small Molecules [J].

Blom, Burgert ;

Stoelzel, Miriam ;

Driess, Matthias .

CHEMISTRY-A EUROPEAN JOURNAL, 2013, 19 (01) :40-62

[7] From a Zwitterionic Phosphasilene to Base Stabilized Silyliumylidene-Phosphide and Bis(silylene) Complexes [J].

Breit, Nora C. ;

Szilvasi, Tibor ;

Suzuki, Tsuyoshi ;

Gallego, Daniel ;

Inoue, Shigeyoshi .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2013, 135 (47) :17958-17968

[8] Preparation, structure and catalytic properties of a binuclear Pd(0) complex with bridging silylene ligands [J].

Fürstner, A ;

Krause, H ;

Lehmann, CW .

CHEMICAL COMMUNICATIONS, 2001, (22) :2372-2373

[9] Silylenenickel(0) or silyl(silylene)platinum(II) complexes by reaction of Si[(NCH2But)2C6H4-1,2] with [NiCl2(PPh3)2], [Ni(cod)2], or [PtCl2(PPh3)2] [J].

Gehrhus, B ;

Hitchcock, PB ;

Lappert, MF ;

Maciejewski, H .

ORGANOMETALLICS, 1998, 17 (26) :5599-5601

[10] A FISCHER-TYPE SILYLENE COMPLEX OF PLATINUM - [TRANS-(CY3P)2(H)PT=SI(SET)2]BPH4 [J].

GRUMBINE, SD ;

TILLEY, TD ;

ARNOLD, FP ;

RHEINGOLD, AL .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1993, 115 (17) :7884-7885

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