Pyrolysis of coal measure source rocks at highly to over mature stage and its geological implications

被引：13

作者：

Gao Jinliang ^{[1
]}

Ni Yunyan ^{[1
]}

Li Wei ^{[1
]}

Yuan Yilin ^{[1
]}

机构：

[1] PetroChina, Res Inst Petr Explorat & Dev, Beijing 100083, Peoples R China

来源：

PETROLEUM EXPLORATION AND DEVELOPMENT | 2020年 / 47卷 / 04期

基金：

中国国家自然科学基金;

关键词：

coal measure source rocks; high-over maturation; coal-derived gas; thermal simulation experiment; ORGANIC-RICH SHALES; GAS GENERATION; HYDROCARBON GASES; ISOTOPE COMPOSITION; WATER-CONTENT; HYDROGEN; KEROGEN; MINERALS; METHANE; CO2;

D O I：

10.1016/S1876-3804(20)60092-1

中图分类号：

TE [石油、天然气工业]; TK [能源与动力工程];

学科分类号：

0807 ; 0820 ;

摘要：

The influence of water on gas generation from humic type organic matter at highly to over mature stage was investigated with thermal simulation experiments at high temperature and pressure. The result of the experiments indicates that the effect of water on gas generation was controlled by the thermal maturity of organic matter. Water could enhance gas generation and increase hydrocarbon gas yields significantly at over mature stage of humic type organic matter. Hydrogen isotopic compositions of coal-derived gases generated at highly to over mature stage were mainly controlled by thermal maturity of source rocks, but also affected by formation water. Highly and over mature coal measure source rocks are widely distributed in China. The hydrocarbon gas generation capacity of coal measure source rocks and resource potential of coal-derived gases in deep formations would be significantly enhanced assuming that formation water could be involved in the thermal cracking of highly to over mature organic matter in real geological settings.

引用

页码：773 / 780

页数：8

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