C2-symmetrical diazabutadiene complexes of platinum(II) and the promotion of cationic polymerization

被引：23
作者：
Albietz, PJ [1 ]
Yang, KY [1 ]
Eisenberg, R [1 ]
机构：
[1] Univ Rochester, Dept Chem, Rochester, NY 14627 USA
来源：
ORGANOMETALLICS | 1999年 / 18卷 / 15期
关键词：
D O I：
10.1021/om9903947
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The synthesis, characterization, and reaction chemistry of a cationic Pt(II) solvento complex (2) are described. The complex demonstrates the unprecedented ability to promote polymerization of the electron-rich olefins ethyl vinyl ether (EVE), N-vinylcarbazole (NVC), and 2,3-dihydrofuran (DHF) via cationic initiation and subsequent propagation of the carbocation.
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页码：2747 / 2749
页数：3
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