Aqueous RAFT/MADIX Polymerization: Same Monomers, New Polymers?

被引：0

作者：

Destarac, Mathias ^{[1
]}

Blidi, Issam ^{[1
]}

Coutelier, Olivier ^{[1
]}

Guinaudeau, Aymeric ^{[1
]}

Mazieres, Stephane ^{[1
]}

Van Gramberen, Eric ^{[2
]}

Wilson, James ^{[2
]}

机构：

[1] Univ Toulouse 3, UMR CNRS 5069, Lab Heterochim Fondamentale & Appl, Bat 2R1,118 Route Narbonne, F-31062 Toulouse 9, France

[2] Ctr Rech & Technol Aubervilliers, Rhodia Operat, F-93308 Aubervilliers, France

来源：

PROGRESS IN CONTROLLED RADICAL POLYMERIZATION: MECHANISMS AND TECHNIQUES | 2012年 / 1100卷

关键词：

HYDROPHILIC BLOCK-COPOLYMERS; VINYL PHOSPHONIC ACID; RADICAL POLYMERIZATION; N-VINYLPYRROLIDONE; AGENTS; RAFT; SURFACTANTS; ACETATE; GROWTH; MEDIA;

D O I：

暂无

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

Thanks to their specific reactivity in RAFT/MADIX polymerization, O-ethyl xanthates are chain transfer agents of choice for controlling the polymerization of "less-activated" monomers (LAMs). In particular, hydrophilic LAMs can be polymerized in water by means of either water-soluble or hydrophobic xanthates in some appropriate conditions. Through the description of successful aqueous RAFT/MADIX polymerization of N-vinylpyrrolidone, diallydimethylammonium chloride and vinylphosphonic acid monomers, which strongly differ in their chemical nature and physicochemical properties of the resulting polymers, it is expected that various original water-soluble copolymers with complex architectures will be available in the future.

引用

页码：259 / +

页数：3

共 35 条

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