Synthesis of Ln(III) chloride tetraphenylporphyrin complexes

被引：24

作者：

Foley, TJ

Abboud, KA

Boncella, JM ^{[1
]}

机构：

[1] Univ Florida, Dept Chem, Gainesville, FL 32611 USA

[2] Univ Florida, Ctr Catalysis, Gainesville, FL 32611 USA

来源：

INORGANIC CHEMISTRY | 2002年 / 41卷 / 07期

关键词：

D O I：

10.1021/ic015612e

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The isolation and identification of the first examples of anhydrous lanthanide chloride tetraphenylporphyrin complexes have been described. The purple complexes were generated by the reaction of dilithiotetraphenylporphyrin bis(dimethoxyethane) with lanthanide trichloride tris(tetrahydrofuran) salts to yield the products in up to 85% yield. The crystal structures for the holmium and ytterbium complexes are also presented.

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页码：1704 / 1706

页数：3

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