Catalytic and Structural Studies of Hoveyda-Grubbs Type Pre-Catalysts Bearing Modified Ether Ligands

被引：16

作者：

Guidone, Stefano ^{[2
]}

Blondiaux, Enguerrand ^{[2
]}

Samojlowicz, Cezary ^{[1
]}

Gulajski, Lukasz ^{[3
]}

Kedziorek, Mariusz ^{[3
]}

Malinska, Maura ^{[3
]}

Pazio, Aleksandra ^{[3
]}

Wozniak, Krzysztof ^{[3
]}

Grela, Karol ^{[1
,3
]}

Doppiu, Angelino ^{[4
]}

Cazin, Catherine S. J. ^{[2
]}

机构：

[1] Polish Acad Sci, Inst Organ Chem, PL-01224 Warsaw, Poland

[2] Univ St Andrews, EaStCHEM Sch Chem, St Andrews KY16 9ST, Fife, Scotland

[3] Warsaw Univ, Dept Chem, PL-02093 Warsaw, Poland

[4] Umicore AG & Co KG, D-63457 Hanau, Germany

来源：

ADVANCED SYNTHESIS & CATALYSIS | 2012年 / 354卷 / 14-15期

关键词：

N-heterocyclic carbenes; olefin metathesis; ring-closing metathesis; ruthenium; OLEFIN METATHESIS CATALYSTS; RUTHENIUM-INDENYLIDENE COMPLEXES; N-HETEROCYCLIC CARBENES; CROSS-METATHESIS; MECHANISM; ADMET; BENZYLIDENE; DERIVATIVES; EFFICIENT; BEHAVIOR;

D O I：

10.1002/adsc.201200385

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

Catalytic and crystallographic studies of HoveydaGrubbs type pre-catalysts M51TM and M52TM were performed. These two new instruments in the olefin metathesis catalyst toolbox were shown to be active at ambient temperature and at low loading, leading to clean formation of ring-closing, ring-closing enyne and cross metathesis products.

引用

页码：2734 / 2742

页数：9

共 44 条

[1] Comparative investigation of Hoveyda-Grubbs catalysts bearing modified N-heterocyclic carbene ligands
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Linden, Anthony
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[2] New N-Heterocyclic Carbene Ligands in Grubbs and Hoveyda-Grubbs Catalysts
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[3] Influence of the anionic ligands on properties and reactivity of Hoveyda-Grubbs catalysts
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Osman, Osman, I
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[4] Synthesis of siloxy-modified second generation Hoveyda-Grubbs catalysts and their catalytic activity
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JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2009, 694 (24) : 3918 - 3922
[5] Expanding the Family of Hoveyda-Grubbs Catalysts Containing Unsymmetrical NHC Ligands
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[6] Experimental and theoretical study of Hoveyda-Grubbs catalysts modified by perfluorohexyl ponytail in the alkoxybenzylidene ligand
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[7] Impact of the olefin structure on the catalytic cycle and decomposition rates of Hoveyda-Grubbs metathesis catalysts
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PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2020, 22 (23) : 13062 - 13069
[8] Mechanistic Studies of Hoveyda-Grubbs Metathesis Catalysts Bearing S-, Br-, I-, and N-coordinating Naphthalene Ligands
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[9] Recent advances for controlling the activity and the recoverability of Hoveyda-Grubbs type olefin metathesis catalysts
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[10] A computational study of structures and catalytic activities of Hoveyda-Grubbs analogues bearing coumarin or isopropoxycoumarin moiety
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