A new method for dialkyl peroxides synthesis in ionic liquids as solvents

被引:15
作者
Baj, S [1 ]
Chrobok, A [1 ]
Derfla, S [1 ]
机构
[1] Silesian Tech Univ, Dept Chem Organ Technol & Petrochem, Gliwice, Poland
关键词
D O I
10.1039/b513863a
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Organic hydroperoxides undergo smooth nucleophilic displacement reactions with alkyl bromides in the presence of 30% water solution of NaOH in several ionic liquids (ILs) at room temperature to afford the corresponding dialkyl peroxides in excellent yields under extremely mild conditions. Additionally, symmetrical dialkyl peroxides were obtained in ionic liquids as solvent with good yields.
引用
收藏
页码:292 / 295
页数:4
相关论文
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