Water as a direct hydrogen donor in supercritical carbon dioxide:: A novel and efficient Zn-H2O-CO2 system for chemoselective reduction of nitrobenzenes to anilines

被引：14

作者：

Jiang Huan-Feng ^{[1
]}

Dong Yao-Sen ^{[1
]}

机构：

[1] S China Univ Technol, Coll Chem, Guangzhou 510640, Guangdong, Peoples R China

来源：

CHINESE JOURNAL OF CHEMISTRY | 2008年 / 26卷 / 08期

基金：

中国国家自然科学基金;

关键词：

catalytic transfer hydrogenation (CTH); Zn-H2O-CO2; nitrobenzene; aniline; chemoselectivity;

D O I：

10.1002/cjoc.200890256

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

An eco-friendly and cheap Zn-H2O-CO2 system was presented for chemoselective reduction of nitrobenzens to anilines with high yields (80%-97% isolated yields) ill supercritical carbon dioxide. This process brings together the very important green chemistry technologies-the use of carbon dioxide as a solvent and the use of water as a hydrogen donor.

引用

页码：1407 / 1410

页数：4

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