One-pot efficient synthesis of disulfides from alkyl halides and alkyl tosylates using thiourea and elemental sulfur without contamination by higher polysulfides

被引：17

作者：

Abbasi, Mohammad ^{[1
]}

Mohammadizadeh, Mohammad Reza ^{[2
]}

Taghavi, Zeinab Khatoon ^{[2
]}

机构：

[1] Persian Gulf Univ, Dept Fisheries & Aquaculture, Coll Agr & Nat Resources, Bushehr 75169, Iran

[2] Persian Gulf Univ, Chem Depatment, Fac Sci, Bushehr 75169, Iran

来源：

JOURNAL OF THE IRANIAN CHEMICAL SOCIETY | 2013年 / 10卷 / 02期

关键词：

Disulfide; Alkyl halide; Alkyl tosylate; Sulfur; Thiourea; PHASE-TRANSFER CONDITIONS; SYMMETRICAL DISULFIDES; CATALYZED-REACTIONS; BOND FORMATION; REDUCTION; THIOLS;

D O I：

10.1007/s13738-012-0141-0

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

An efficient and odorless synthesis of disulfides from alkyl halides using thiourea and elemental sulfur in the presence of sodium carbonate in wet polyethylene glycol (PEG 200) at 40 A degrees C without contamination by higher polysulfides has been developed. This procedure was then extended to preparation of disulfides from alkyl tosylates at 70 A degrees C.

引用

页码：201 / 205

页数：5

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