Dendrimers based on ruthenium(II) and osmium(II) polypyridine complexes and the approach of using complexes as ligands and complexes as metals

被引:157
|
作者
Serroni, S [1 ]
Campagna, S [1 ]
Puntoriero, F [1 ]
Di Pietro, C [1 ]
McClenaghan, ND [1 ]
Loiseau, F [1 ]
机构
[1] Univ Messina, Dipartimento Chim Inorgan Chim Analit & Chim Fis, I-98166 Messina, Italy
关键词
D O I
10.1039/b008670n
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The use of the "complexes as ligands and complexes as metals" synthetic strategy for the preparation of luminescent and redox-active Ru(II) and Os(II) dendrimers, the dominant synthetic approach for this novel class of compounds, is reviewed. A few comments on the photophysical and redox properties of the metal dendrimers are provided and an overview of alternative synthetic approaches is also presented.
引用
收藏
页码:367 / 375
页数:9
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