Au and Fe magnetic moments in disordered Au-Fe alloys

被引:26
|
作者
Wilhelm, F. [2 ]
Poulopoulos, P. [1 ]
Kapaklis, V. [1 ,3 ]
Kappler, J. -P. [4 ]
Jaouen, N. [2 ]
Rogalev, A. [2 ]
Yaresko, A. N. [5 ]
Politis, C. [3 ,6 ]
机构
[1] Univ Patras, Dept Mat Sci, Patras 26504, Greece
[2] European Synchrotron Radiat Facil, F-38043 Grenoble, France
[3] Univ Patras, Dept Engn Sci, Sch Engn, Patras 26504, Greece
[4] IPCMS, F-67037 Strasbourg, France
[5] Max Planck Inst Phys Komplexer Syst, D-01187 Dresden, Germany
[6] Forschungszentrum Karlsruhe, Inst Nanotechnol, D-76021 Karlsruhe, Germany
关键词
D O I
10.1103/PhysRevB.77.224414
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
We report on the magnetic moments of Au and Fe in fcc and bcc disordered Au-Fe alloys determined via a combination of x-ray magnetic circular dichroic measurements at the L-3,L-2 edges of Au and superconducting quantum interference device magnetometry. The 5d induced magnetic moment of Au in the fcc alloys scales with the number N of nearest Fe neighbors, from M-Au=0.1 mu(B)/atom for N=3 to M-Au=0.2 mu(B)/atom for N=6. Fe in these alloys is in a high-spin state, which carries a total magnetic moment of about 3 mu(B)/atom. The maximum value of 5d induced magnetic moment of Au is 0.33 mu(B)/atom and is exhibited when Au is placed as an impurity in a bcc Fe environment. The ratio of the orbital-to-spin 5d magnetic moment of Au is M-L/M-S approximate to 0.2 in all samples. The experimental results are discussed with respect to first principles calculations.
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页数:6
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