Chemistry of the Synthetic Strigolactone Mimic GR24

被引:6
作者
Bromhead, Liam J. [1 ]
Smith, Jason [2 ]
McErlean, Christopher S. P. [1 ]
机构
[1] Univ Sydney, Sch Chem, Sydney, NSW 2006, Australia
[2] Univ Tasmania, Sch Phys Sci Chem, Hobart, Tas 7001, Australia
关键词
BIOLOGICAL-ACTIVITY; ENANTIOSELECTIVE SYNTHESIS; ASYMMETRIC-SYNTHESIS; GERMINATION; EFFICIENT; STRIGA; STEREOISOMERS; OROBANCHE; ANALOGS; PLANT;
D O I
10.1071/CH15298
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
This research paper describes a second-generation, enantioselective synthesis of (+)-GR24. This new strategy circumvents the need for ozonolysis, which may not be suitable for reactions performed on scale. This flexible new approach is then used to synthesise a novel bromo-GR24 analogue. Finally, the optimal solvent for making GR24 stock solutions is identified.
引用
收藏
页码:1221 / 1227
页数:7
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