Chemistry of the Synthetic Strigolactone Mimic GR24

被引：6

作者：

Bromhead, Liam J. ^{[1
]}

Smith, Jason ^{[2
]}

McErlean, Christopher S. P. ^{[1
]}

机构：

[1] Univ Sydney, Sch Chem, Sydney, NSW 2006, Australia

[2] Univ Tasmania, Sch Phys Sci Chem, Hobart, Tas 7001, Australia

来源：

AUSTRALIAN JOURNAL OF CHEMISTRY | 2015年 / 68卷 / 08期

关键词：

BIOLOGICAL-ACTIVITY; ENANTIOSELECTIVE SYNTHESIS; ASYMMETRIC-SYNTHESIS; GERMINATION; EFFICIENT; STRIGA; STEREOISOMERS; OROBANCHE; ANALOGS; PLANT;

D O I：

10.1071/CH15298

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

This research paper describes a second-generation, enantioselective synthesis of (+)-GR24. This new strategy circumvents the need for ozonolysis, which may not be suitable for reactions performed on scale. This flexible new approach is then used to synthesise a novel bromo-GR24 analogue. Finally, the optimal solvent for making GR24 stock solutions is identified.

引用

页码：1221 / 1227

页数：7

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